Approximating the Temperature–Entropy Saturation Curve of ORC Working Fluids From the Ideal Gas Isobaric Heat Capacity

Recently, we proposed an approximate expression for the liquid−vapor saturation curves of pure fluids in a temperature−entropy diagram that requires the use of parameters related to the molar heat capacity along the vapor branch of the saturation curve. In the present work, we es...

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Bibliographic Details
Main Authors: Juan A. White, Santiago Velasco
Format: Article
Language:English
Published: MDPI AG 2019-08-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/12/17/3266
Description
Summary:Recently, we proposed an approximate expression for the liquid−vapor saturation curves of pure fluids in a temperature−entropy diagram that requires the use of parameters related to the molar heat capacity along the vapor branch of the saturation curve. In the present work, we establish a connection between these parameters and the ideal-gas isobaric molar heat capacity. The resulting new approximation yields good results for most working fluids in Organic Rankine Cycles, improving the previous approximation for very dry fluids. The ideal-gas isobaric molar heat capacity can be obtained from most Thermophysical Properties databases for a very large number of substances for which the present approximation scheme can be applied.
ISSN:1996-1073