(4-Carboxy-2-sulfonatobenzoato-κ2O1,O2)bis(1,10-phenanthroline-κ2N,N′)manganese(II)
In the title complex, [Mn(C8H4O7S)(C12H8N2)2], the MnII atom is chelated by one 4-carboxy-2-sulfonatobenzoate anion and two phenathroline (phen) ligands in a distorted octahedral MnN4O2 geometry. The benzene ring of the 4-carboxy-2-sulfonatobenzoate anion is twisted with respect to the two phen ring...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810023743 |
| Summary: | In the title complex, [Mn(C8H4O7S)(C12H8N2)2], the MnII atom is chelated by one 4-carboxy-2-sulfonatobenzoate anion and two phenathroline (phen) ligands in a distorted octahedral MnN4O2 geometry. The benzene ring of the 4-carboxy-2-sulfonatobenzoate anion is twisted with respect to the two phen ring systems at dihedral angles of 66.38 (9) and 53.56 (9)°. In the crystal, intermolecular O—H...O and C—H...O hydrogen bonding links the molecules into chains running parallel to [100]. Intermolecular π–π stacking is also observed between parallel phen ring systems, the face-to-face distance being 3.432 (6) Å. |
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| ISSN: | 1600-5368 |