Structural, Wetting and Magnetic Properties of Sputtered Fe<sub>70</sub>Pd<sub>30</sub> Thin Film with Nanostructured Surface Induced by Dealloying Process

FePd alloys in the thin film form represent a multipurpose and versatile material with relevant chemical and physical properties studied in different research fields. Moreover, the ability to manipulate and fine-tune the film surface with nanometric scale precision represents a degree of freedom use...

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Bibliographic Details
Main Authors: Gabriele Barrera, Federica Celegato, Matteo Cialone, Marco Coïsson, Paola Rizzi, Paola Tiberto
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/11/2/282
Description
Summary:FePd alloys in the thin film form represent a multipurpose and versatile material with relevant chemical and physical properties studied in different research fields. Moreover, the ability to manipulate and fine-tune the film surface with nanometric scale precision represents a degree of freedom useful to adapt these thin film properties to the demands of different desired applications. In this manuscript, Fe<sub>70</sub>Pd<sub>30</sub> (at. %) thin films are prepared with a thickness of 50 and 200 nm by means of the widely used co-sputtering deposition technique. Subsequently, selective removal of the iron element from the alloy and the consequent surface diffusion of the palladium was induced by a dealloying treatment under free corrosion conditions in hydrochloric acid. The size and shape of the grains of the as-deposited thin films determine the dissolution rate of the iron element with a direct consequence not only on the surface morphology and the stoichiometry of the alloy but also on the wetting and magnetic properties of the sample. X-ray diffraction, Scanning Electron Microscopy (SEM) images, contact angle and magnetic measurements have been performed to provide a thorough characterisation of the fundamental properties of these nanostructured bimetallic thin films.
ISSN:2079-4991