Crystal structure of N-(quinolin-6-yl)hydroxylamine

Crystal structure of N-(quinolin-6-yl)hydroxylamine

The title compound, C9H8N2O, crystallized with four independent molecules in the asymmetric unit. The four molecules are linked via one O—H...N and two N—H...N hydrogen bonds, forming a tetramer-like unit. In the crystal, molecules are further linked by O—H...N and N—H...O hydrogen bonds forming lay...

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Bibliographic Details
Main Authors: Anuruddha Rajapakse, Roman Hillebrand, Sarah M. Lewis, Zachary D. Parsons, Charles L. Barnes, Kent S. Gates
Format: Article
Language:English
Published: International Union of Crystallography 2014-11-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
N-arylhydroxylamine
hydroxylamine
N-(quinolin-6-yl)hydroxylamine
quinoline
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681402193X
Description
Summary:The title compound, C9H8N2O, crystallized with four independent molecules in the asymmetric unit. The four molecules are linked via one O—H...N and two N—H...N hydrogen bonds, forming a tetramer-like unit. In the crystal, molecules are further linked by O—H...N and N—H...O hydrogen bonds forming layers parallel to (001). These layers are linked via C—H...O hydrogen bonds and a number of weak C—H...π interactions, forming a three-dimensional structure. The crystal was refined as a non-merohedral twin with a minor twin component of 0.319.
ISSN:1600-5368

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