Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene

Full utilization of ZSM-5 shape-selectivity is restricted by crystal external surface acid sites and co-existence of two different sized channels. Here, the authors synthesize reverse Al zoned ZSM-5 with sinusoidal channel preferentially opened to its inert external surface to achieve 99.3% p-xylene...

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Main Authors:	Chuanfu Wang, Lei Zhang, Xin Huang, Yufei Zhu, Gang (Kevin) Li, Qinfen Gu, Jingyun Chen, Linge Ma, Xiujie Li, Qihua He, Junbo Xu, Qi Sun, Chuqiao Song, Mi Peng, Junliang Sun, Ding Ma
Format:	Article
Language:	English
Published:	Nature Publishing Group 2019-09-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-019-12285-4

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spelling	doaj-1ec4943f46554dc89c8ddcaae263bf532021-05-11T12:25:22ZengNature Publishing GroupNature Communications2041-17232019-09-011011810.1038/s41467-019-12285-4Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xyleneChuanfu Wang0Lei Zhang1Xin Huang2Yufei Zhu3Gang (Kevin) Li4Qinfen Gu5Jingyun Chen6Linge Ma7Xiujie Li8Qihua He9Junbo Xu10Qi Sun11Chuqiao Song12Mi Peng13Junliang Sun14Ding Ma15National Institute of Clean-and-Low-Carbon Energy (NICE)Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking UniversityNational Institute of Clean-and-Low-Carbon Energy (NICE)National Institute of Clean-and-Low-Carbon Energy (NICE)Department of Chemical and Biomolecular Engineering, The University of MelbourneAustralian SynchrotronNational Institute of Clean-and-Low-Carbon Energy (NICE)National Institute of Clean-and-Low-Carbon Energy (NICE)Dalian Institute of Chemical Physics, Chinese Academy of SciencesPeking University Health Science CentreInstitute of Process Engineering, Chinese Academy of SciencesNational Institute of Clean-and-Low-Carbon Energy (NICE)Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking UniversityBeijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking UniversityBeijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking UniversityBeijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking UniversityFull utilization of ZSM-5 shape-selectivity is restricted by crystal external surface acid sites and co-existence of two different sized channels. Here, the authors synthesize reverse Al zoned ZSM-5 with sinusoidal channel preferentially opened to its inert external surface to achieve 99.3% p-xylene selectivity.https://doi.org/10.1038/s41467-019-12285-4
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Chuanfu Wang Lei Zhang Xin Huang Yufei Zhu Gang (Kevin) Li Qinfen Gu Jingyun Chen Linge Ma Xiujie Li Qihua He Junbo Xu Qi Sun Chuqiao Song Mi Peng Junliang Sun Ding Ma
spellingShingle	Chuanfu Wang Lei Zhang Xin Huang Yufei Zhu Gang (Kevin) Li Qinfen Gu Jingyun Chen Linge Ma Xiujie Li Qihua He Junbo Xu Qi Sun Chuqiao Song Mi Peng Junliang Sun Ding Ma Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene Nature Communications
author_facet	Chuanfu Wang Lei Zhang Xin Huang Yufei Zhu Gang (Kevin) Li Qinfen Gu Jingyun Chen Linge Ma Xiujie Li Qihua He Junbo Xu Qi Sun Chuqiao Song Mi Peng Junliang Sun Ding Ma
author_sort	Chuanfu Wang
title	Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene
title_short	Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene
title_full	Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene
title_fullStr	Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene
title_full_unstemmed	Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene
title_sort	maximizing sinusoidal channels of hzsm-5 for high shape-selectivity to p-xylene
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2019-09-01
description	Full utilization of ZSM-5 shape-selectivity is restricted by crystal external surface acid sites and co-existence of two different sized channels. Here, the authors synthesize reverse Al zoned ZSM-5 with sinusoidal channel preferentially opened to its inert external surface to achieve 99.3% p-xylene selectivity.
url	https://doi.org/10.1038/s41467-019-12285-4
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Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene

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