Catalytic Enantioselective Aryl Transfer to Aldehydes Using Chiral 2,2’-Bispyrrolidine-Based Salan Ligands

Chiral C2-symmetric diamines have emerged as versatile auxiliaries or ligands in numerous asymmetric transformations. Chiral 2,2’-bispyrrolidine-based salan ligands were prepared and applied to the asymmetric aryl transfer to aldehydes with arylboronic acids as the source of transferable aryl groups...

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Main Authors:	Yixiang Cheng, Zhijie Mao, Xuefeng Jia, Chengjian Zhu, Aijun Lin
Format:	Article
Language:	English
Published:	MDPI AG 2011-04-01
Series:	Molecules
Subjects:	2,2’-bispyrrolidine salan ligands aryl transfer arylboronic acid enantioselectivity
Online Access:	http://www.mdpi.com/1420-3049/16/4/2971/

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record_format	Article
spelling	doaj-1f33571345f94982a0ea6974c28949432020-11-24T22:39:54ZengMDPI AGMolecules1420-30492011-04-011642971298110.3390/molecules16042971Catalytic Enantioselective Aryl Transfer to Aldehydes Using Chiral 2,2’-Bispyrrolidine-Based Salan LigandsYixiang ChengZhijie MaoXuefeng JiaChengjian ZhuAijun LinChiral C2-symmetric diamines have emerged as versatile auxiliaries or ligands in numerous asymmetric transformations. Chiral 2,2’-bispyrrolidine-based salan ligands were prepared and applied to the asymmetric aryl transfer to aldehydes with arylboronic acids as the source of transferable aryl groups. The corresponding diarylmethanols were obtained in high yields with moderate to good enantioselectivitives of up to 83% ee. http://www.mdpi.com/1420-3049/16/4/2971/2,2’-bispyrrolidinesalan ligandsaryl transferarylboronic acidenantioselectivity
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Yixiang Cheng Zhijie Mao Xuefeng Jia Chengjian Zhu Aijun Lin
spellingShingle	Yixiang Cheng Zhijie Mao Xuefeng Jia Chengjian Zhu Aijun Lin Catalytic Enantioselective Aryl Transfer to Aldehydes Using Chiral 2,2’-Bispyrrolidine-Based Salan Ligands Molecules 2,2’-bispyrrolidine salan ligands aryl transfer arylboronic acid enantioselectivity
author_facet	Yixiang Cheng Zhijie Mao Xuefeng Jia Chengjian Zhu Aijun Lin
author_sort	Yixiang Cheng
title	Catalytic Enantioselective Aryl Transfer to Aldehydes Using Chiral 2,2’-Bispyrrolidine-Based Salan Ligands
title_short	Catalytic Enantioselective Aryl Transfer to Aldehydes Using Chiral 2,2’-Bispyrrolidine-Based Salan Ligands
title_full	Catalytic Enantioselective Aryl Transfer to Aldehydes Using Chiral 2,2’-Bispyrrolidine-Based Salan Ligands
title_fullStr	Catalytic Enantioselective Aryl Transfer to Aldehydes Using Chiral 2,2’-Bispyrrolidine-Based Salan Ligands
title_full_unstemmed	Catalytic Enantioselective Aryl Transfer to Aldehydes Using Chiral 2,2’-Bispyrrolidine-Based Salan Ligands
title_sort	catalytic enantioselective aryl transfer to aldehydes using chiral 2,2’-bispyrrolidine-based salan ligands
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2011-04-01
description	Chiral C2-symmetric diamines have emerged as versatile auxiliaries or ligands in numerous asymmetric transformations. Chiral 2,2’-bispyrrolidine-based salan ligands were prepared and applied to the asymmetric aryl transfer to aldehydes with arylboronic acids as the source of transferable aryl groups. The corresponding diarylmethanols were obtained in high yields with moderate to good enantioselectivitives of up to 83% ee.
topic	2,2’-bispyrrolidine salan ligands aryl transfer arylboronic acid enantioselectivity
url	http://www.mdpi.com/1420-3049/16/4/2971/
work_keys_str_mv	AT yixiangcheng catalyticenantioselectivearyltransfertoaldehydesusingchiral22bispyrrolidinebasedsalanligands AT zhijiemao catalyticenantioselectivearyltransfertoaldehydesusingchiral22bispyrrolidinebasedsalanligands AT xuefengjia catalyticenantioselectivearyltransfertoaldehydesusingchiral22bispyrrolidinebasedsalanligands AT chengjianzhu catalyticenantioselectivearyltransfertoaldehydesusingchiral22bispyrrolidinebasedsalanligands AT aijunlin catalyticenantioselectivearyltransfertoaldehydesusingchiral22bispyrrolidinebasedsalanligands
_version_	1725707001624788992

Catalytic Enantioselective Aryl Transfer to Aldehydes Using Chiral 2,2’-Bispyrrolidine-Based Salan Ligands

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