Bis[2-(diphenylphosphanyl-κP)benzaldehyde]iodidogold(I)

Bis[2-(diphenylphosphanyl-κP)benzaldehyde]iodidogold(I)

In the title compound, [AuI(C19H15OP)2], the complete molecule is generated by the application of twofold symmetry. The AuI atom is in a trigonal–planar geometry within an IP2 donor set with the greatest distortion seen in the P—Au—P angle [128.49&#8...

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Bibliographic Details
Main Authors: Michael L. Williams, Samuel P. C. Dunstan, Peter C. Healy, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812011609
Description
Summary:In the title compound, [AuI(C19H15OP)2], the complete molecule is generated by the application of twofold symmetry. The AuI atom is in a trigonal–planar geometry within an IP2 donor set with the greatest distortion seen in the P—Au—P angle [128.49 (3) °]. Close intramolecular Au...O interactions [3.172 (3) Å] are observed. No specific intermolecular interactions are noted in the crystal packing.
ISSN:1600-5368

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