Anomaly in the Chain Length Dependence of n-Alkane Diffusion in ZIF-4 Metal-Organic Frameworks

Anomaly in the Chain Length Dependence of n-Alkane Diffusion in ZIF-4 Metal-Organic Frameworks

Molecular diffusion is commonly found to slow down with increasing molecular size. Deviations from this pattern occur in some host materials with pore sizes approaching the diameters of the guest molecules. A variety of theoretical models have been suggested to explain deviations from this pattern,...

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Bibliographic Details
Main Authors: Seungtaik Hwang, Arun Gopalan, Maximilian Hovestadt, Frank Piepenbreier, Christian Chmelik, Martin Hartmann, Randall Q. Snurr, Jörg Kärger
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Molecules
Subjects:
ZIF-4
n-alkanes
transport diffusivity
commensurate/incommensurate adsorption
GCMC simulation
Online Access:http://www.mdpi.com/1420-3049/23/3/668

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