Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2N,N′)cobalt(II) dichloromethane hemisolvate

Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2N,N′)cobalt(II) dichloromethane hemisolvate

The title compound, [CoCl2(C21H17ClN2)]·0.5CH2Cl2, crystallizes from dichloromethane as a 2:1 solvate [CoCl2L]2·CH2Cl2 (L is 2-chloro-9-mesityl-1,10-phenanthroline). There are two independent CoCl2L molecules in the asymmetric unit and both molecules have similar conformations. The...

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Main Authors: Biao Wu, Cui Zhang, Peiju Yang, Yue Yang
Format: Article
Language:English
Published: International Union of Crystallography 2008-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808007320
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spelling doaj-203654501c3d4e029bacb8d0ebcaa1a82020-11-25T00:12:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645m623m62310.1107/S1600536808007320Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2N,N′)cobalt(II) dichloromethane hemisolvateBiao WuCui ZhangPeiju YangYue YangThe title compound, [CoCl2(C21H17ClN2)]·0.5CH2Cl2, crystallizes from dichloromethane as a 2:1 solvate [CoCl2L]2·CH2Cl2 (L is 2-chloro-9-mesityl-1,10-phenanthroline). There are two independent CoCl2L molecules in the asymmetric unit and both molecules have similar conformations. They are connected by a weak C—H...π interaction involving the mesityl ring. The cobalt center is four-coordinated by the two N-atom donors of the bidentate ligand and two chloride ions in a distorted tetrahedral geometry. The packing of the molecules is stabilized by weak slipped π–π stacking interactions between symmetry-related phenanthroline groups.http://scripts.iucr.org/cgi-bin/paper?S1600536808007320
collection DOAJ
language English
format Article
sources DOAJ
author Biao Wu
Cui Zhang
Peiju Yang
Yue Yang
spellingShingle Biao Wu
Cui Zhang
Peiju Yang
Yue Yang
Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2N,N′)cobalt(II) dichloromethane hemisolvate
Acta Crystallographica Section E
author_facet Biao Wu
Cui Zhang
Peiju Yang
Yue Yang
author_sort Biao Wu
title Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2N,N′)cobalt(II) dichloromethane hemisolvate
title_short Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2N,N′)cobalt(II) dichloromethane hemisolvate
title_full Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2N,N′)cobalt(II) dichloromethane hemisolvate
title_fullStr Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2N,N′)cobalt(II) dichloromethane hemisolvate
title_full_unstemmed Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2N,N′)cobalt(II) dichloromethane hemisolvate
title_sort dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2n,n′)cobalt(ii) dichloromethane hemisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-05-01
description The title compound, [CoCl2(C21H17ClN2)]·0.5CH2Cl2, crystallizes from dichloromethane as a 2:1 solvate [CoCl2L]2·CH2Cl2 (L is 2-chloro-9-mesityl-1,10-phenanthroline). There are two independent CoCl2L molecules in the asymmetric unit and both molecules have similar conformations. They are connected by a weak C—H...π interaction involving the mesityl ring. The cobalt center is four-coordinated by the two N-atom donors of the bidentate ligand and two chloride ions in a distorted tetrahedral geometry. The packing of the molecules is stabilized by weak slipped π–π stacking interactions between symmetry-related phenanthroline groups.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808007320
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AT cuizhang dichlorido2chloro9mesityl110phenanthroline9542nn8242cobaltiidichloromethanehemisolvate
AT peijuyang dichlorido2chloro9mesityl110phenanthroline9542nn8242cobaltiidichloromethanehemisolvate
AT yueyang dichlorido2chloro9mesityl110phenanthroline9542nn8242cobaltiidichloromethanehemisolvate
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