Performance of Ethane Dehydrogenation over PtSn Loaded onto a Calcined Mg(Al)O LDH with Three Mg:Al Molar Ratios Using a Novel Method

Layered double hydroxide (LDH) is a layered solid containing positively charged layers with negatively charged anions as an interchangeable interlayer. In this research, Mg(Al)O supports were synthesized with three different Mg:Al molar ratios, and bimetallic PtSn catalysts were loaded onto the supp...

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Main Authors: Shuqi Fang, Kang Bi, Qiao Zhang, Lingpeng Chen, Yongming Sun, Hongyu Huang, Longlong Ma, Chenguang Wang
Format: Article
Language:English
Published: MDPI AG 2018-07-01
Series:Catalysts
Subjects:
Online Access:http://www.mdpi.com/2073-4344/8/8/296
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spelling doaj-2051de692c194882bb3375d6e9f74a5b2020-11-24T21:19:09ZengMDPI AGCatalysts2073-43442018-07-018829610.3390/catal8080296catal8080296Performance of Ethane Dehydrogenation over PtSn Loaded onto a Calcined Mg(Al)O LDH with Three Mg:Al Molar Ratios Using a Novel MethodShuqi Fang0Kang Bi1Qiao Zhang2Lingpeng Chen3Yongming Sun4Hongyu Huang5Longlong Ma6Chenguang Wang7School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, ChinaSchool of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510640, ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510640, ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510640, ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510640, ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510640, ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510640, ChinaLayered double hydroxide (LDH) is a layered solid containing positively charged layers with negatively charged anions as an interchangeable interlayer. In this research, Mg(Al)O supports were synthesized with three different Mg:Al molar ratios, and bimetallic PtSn catalysts were loaded onto the supports via the anion exchange method. The properties of ethane dehydrogenation of the PtSn/Mg(Al)O catalysts were investigated. The results show that the structure and properties of the PtSn/Mg(Al)O catalysts were influenced by the Mg:Al molar ratio of the hydrotalcites, which consequently influenced the ethane dehydrogenation performance. When the Mg:Al ratio was 5:1, the ethane dehydrogenation performance was optimal, relative to the Mg:Al ratios of 2:1 and 10:1.http://www.mdpi.com/2073-4344/8/8/296hydrotalciteMg:Al molar ratioanion exchange methodethane dehydrogenation
collection DOAJ
language English
format Article
sources DOAJ
author Shuqi Fang
Kang Bi
Qiao Zhang
Lingpeng Chen
Yongming Sun
Hongyu Huang
Longlong Ma
Chenguang Wang
spellingShingle Shuqi Fang
Kang Bi
Qiao Zhang
Lingpeng Chen
Yongming Sun
Hongyu Huang
Longlong Ma
Chenguang Wang
Performance of Ethane Dehydrogenation over PtSn Loaded onto a Calcined Mg(Al)O LDH with Three Mg:Al Molar Ratios Using a Novel Method
Catalysts
hydrotalcite
Mg:Al molar ratio
anion exchange method
ethane dehydrogenation
author_facet Shuqi Fang
Kang Bi
Qiao Zhang
Lingpeng Chen
Yongming Sun
Hongyu Huang
Longlong Ma
Chenguang Wang
author_sort Shuqi Fang
title Performance of Ethane Dehydrogenation over PtSn Loaded onto a Calcined Mg(Al)O LDH with Three Mg:Al Molar Ratios Using a Novel Method
title_short Performance of Ethane Dehydrogenation over PtSn Loaded onto a Calcined Mg(Al)O LDH with Three Mg:Al Molar Ratios Using a Novel Method
title_full Performance of Ethane Dehydrogenation over PtSn Loaded onto a Calcined Mg(Al)O LDH with Three Mg:Al Molar Ratios Using a Novel Method
title_fullStr Performance of Ethane Dehydrogenation over PtSn Loaded onto a Calcined Mg(Al)O LDH with Three Mg:Al Molar Ratios Using a Novel Method
title_full_unstemmed Performance of Ethane Dehydrogenation over PtSn Loaded onto a Calcined Mg(Al)O LDH with Three Mg:Al Molar Ratios Using a Novel Method
title_sort performance of ethane dehydrogenation over ptsn loaded onto a calcined mg(al)o ldh with three mg:al molar ratios using a novel method
publisher MDPI AG
series Catalysts
issn 2073-4344
publishDate 2018-07-01
description Layered double hydroxide (LDH) is a layered solid containing positively charged layers with negatively charged anions as an interchangeable interlayer. In this research, Mg(Al)O supports were synthesized with three different Mg:Al molar ratios, and bimetallic PtSn catalysts were loaded onto the supports via the anion exchange method. The properties of ethane dehydrogenation of the PtSn/Mg(Al)O catalysts were investigated. The results show that the structure and properties of the PtSn/Mg(Al)O catalysts were influenced by the Mg:Al molar ratio of the hydrotalcites, which consequently influenced the ethane dehydrogenation performance. When the Mg:Al ratio was 5:1, the ethane dehydrogenation performance was optimal, relative to the Mg:Al ratios of 2:1 and 10:1.
topic hydrotalcite
Mg:Al molar ratio
anion exchange method
ethane dehydrogenation
url http://www.mdpi.com/2073-4344/8/8/296
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