catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ2S:S]]

catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ2S:S]]

In the title coordination polymer, [CuBr(C3H5N3S)]n, the CuI atom adopts a tetrahdral CuS2Br2 coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of CuI atoms and gener...

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Main Authors: Chaveng Pakawatchai, Jonathan Charmant, Saowanit Saithong
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812014444
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spelling doaj-20891a743d76424cb123fe175144acad2020-11-24T21:32:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m565m56610.1107/S1600536812014444catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ2S:S]]Chaveng PakawatchaiJonathan CharmantSaowanit SaithongIn the title coordination polymer, [CuBr(C3H5N3S)]n, the CuI atom adopts a tetrahdral CuS2Br2 coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of CuI atoms and generating chains propagating in [100]. Inter-chain N—H...N hydrogen bonds generate layers in the ac plane. Weak intra-chain N—H...Br interactions also occur. http://scripts.iucr.org/cgi-bin/paper?S1600536812014444
collection DOAJ
language English
format Article
sources DOAJ
author Chaveng Pakawatchai
Jonathan Charmant
Saowanit Saithong
spellingShingle Chaveng Pakawatchai
Jonathan Charmant
Saowanit Saithong
catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ2S:S]]
Acta Crystallographica Section E
author_facet Chaveng Pakawatchai
Jonathan Charmant
Saowanit Saithong
author_sort Chaveng Pakawatchai
title catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ2S:S]]
title_short catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ2S:S]]
title_full catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ2S:S]]
title_fullStr catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ2S:S]]
title_full_unstemmed catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ2S:S]]
title_sort catena-poly[copper(i)-di-μ-bromido-copper(i)-bis[μ-4-methyl-1h-1,2,4-triazole-5(4h)-thione-κ2s:s]]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-05-01
description In the title coordination polymer, [CuBr(C3H5N3S)]n, the CuI atom adopts a tetrahdral CuS2Br2 coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of CuI atoms and generating chains propagating in [100]. Inter-chain N—H...N hydrogen bonds generate layers in the ac plane. Weak intra-chain N—H...Br interactions also occur.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812014444
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AT jonathancharmant catenapolycopperidiamp956bromidocopperibisamp9564methyl1h124triazole54hthioneamp9542ss
AT saowanitsaithong catenapolycopperidiamp956bromidocopperibisamp9564methyl1h124triazole54hthioneamp9542ss
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