Poly[[μ4-bis(4-pyridylcarbonyl)piperazine-κ4N:N′:O:O′]bis(thiocyanato-κN)cobalt(II)]

Poly[[μ4-bis(4-pyridylcarbonyl)piperazine-κ4N:N′:O:O′]bis(thiocyanato-κN)cobalt(II)]

In the title compound, [Co(NCS)2(C16H16N4O2)]n, the octahedrally coordinated CoII ion lies on a crystallographic inversion center, with trans isothiocyanate ligands. Pyridyl N-donor atoms and formyl O-donor atoms from exotetradentate bis(4-pyridylcarbonyl)piperazine (4-bpfp) ligands link the Co(NCS)...

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Bibliographic Details
Main Authors: Zachary M. Wilseck, Robert L. LaDuca
Format: Article
Language:English
Published: International Union of Crystallography 2010-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681001915X
Description
Summary:In the title compound, [Co(NCS)2(C16H16N4O2)]n, the octahedrally coordinated CoII ion lies on a crystallographic inversion center, with trans isothiocyanate ligands. Pyridyl N-donor atoms and formyl O-donor atoms from exotetradentate bis(4-pyridylcarbonyl)piperazine (4-bpfp) ligands link the Co(NCS)2 units into a [Co(NCS)2(4-bpfp)]n coordination polymer layer that is oriented parallel to (101). The layers stack along [010] to construct the pseudo-three-dimensional structure.
ISSN:1600-5368

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