Bis[2,4-dibromo-6-(n-propyliminomethyl)phenolato-κ2N,O]cobalt(II)

Bis[2,4-dibromo-6-(n-propyliminomethyl)phenolato-κ2N,O]cobalt(II)

In the title complex, [Co(C10H10Br2NO)2], the CoII atom lies on a twofold rotation axis, the N2O2 units having distorted tetrahedral coordination environments comprising two bidentate chelate 2,4-dibromo-6-(n-propyliminomethyl)phenolate Schiff base ligands [Co—N = 1.989 (...

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Main Authors: Chunyan Li, Rui Li, Shufang Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810032162
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spelling doaj-2227e5f6aa6d458db82cd9ba90dde38f2020-11-25T02:00:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1123m112310.1107/S1600536810032162Bis[2,4-dibromo-6-(n-propyliminomethyl)phenolato-κ2N,O]cobalt(II)Chunyan LiRui LiShufang ZhangIn the title complex, [Co(C10H10Br2NO)2], the CoII atom lies on a twofold rotation axis, the N2O2 units having distorted tetrahedral coordination environments comprising two bidentate chelate 2,4-dibromo-6-(n-propyliminomethyl)phenolate Schiff base ligands [Co—N = 1.989 (3) Å, Co—O = 1.924 (2) Å and O/N—Co—O/N = 94.53 (10)–125.40 (15)°]. In the crystal structure, the molecules are linked via weak intermolecular C—H...O hydrogen bonds [3.334 (5) Å] and there are also short inversion-related intermolecular Br...Br contacts [3.4263 (6) Å] http://scripts.iucr.org/cgi-bin/paper?S1600536810032162
collection DOAJ
language English
format Article
sources DOAJ
author Chunyan Li
Rui Li
Shufang Zhang
spellingShingle Chunyan Li
Rui Li
Shufang Zhang
Bis[2,4-dibromo-6-(n-propyliminomethyl)phenolato-κ2N,O]cobalt(II)
Acta Crystallographica Section E
author_facet Chunyan Li
Rui Li
Shufang Zhang
author_sort Chunyan Li
title Bis[2,4-dibromo-6-(n-propyliminomethyl)phenolato-κ2N,O]cobalt(II)
title_short Bis[2,4-dibromo-6-(n-propyliminomethyl)phenolato-κ2N,O]cobalt(II)
title_full Bis[2,4-dibromo-6-(n-propyliminomethyl)phenolato-κ2N,O]cobalt(II)
title_fullStr Bis[2,4-dibromo-6-(n-propyliminomethyl)phenolato-κ2N,O]cobalt(II)
title_full_unstemmed Bis[2,4-dibromo-6-(n-propyliminomethyl)phenolato-κ2N,O]cobalt(II)
title_sort bis[2,4-dibromo-6-(n-propyliminomethyl)phenolato-κ2n,o]cobalt(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-09-01
description In the title complex, [Co(C10H10Br2NO)2], the CoII atom lies on a twofold rotation axis, the N2O2 units having distorted tetrahedral coordination environments comprising two bidentate chelate 2,4-dibromo-6-(n-propyliminomethyl)phenolate Schiff base ligands [Co—N = 1.989 (3) Å, Co—O = 1.924 (2) Å and O/N—Co—O/N = 94.53 (10)–125.40 (15)°]. In the crystal structure, the molecules are linked via weak intermolecular C—H...O hydrogen bonds [3.334 (5) Å] and there are also short inversion-related intermolecular Br...Br contacts [3.4263 (6) Å]
url http://scripts.iucr.org/cgi-bin/paper?S1600536810032162
work_keys_str_mv AT chunyanli bis24dibromo6npropyliminomethylphenolatoamp9542nocobaltii
AT ruili bis24dibromo6npropyliminomethylphenolatoamp9542nocobaltii
AT shufangzhang bis24dibromo6npropyliminomethylphenolatoamp9542nocobaltii
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