Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate

Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate

In the title rhenium(I) complex, [ReBr(C13H9N3O)(CO)3]·CH2Cl2, the dichloromethane solvent molecule is disordered over two positions with an occupancy ratio of 0.81 (15):0.19 (15). The ReI atom is coordinated by two N atoms from a 2-phenyl-5-(pyridin-2-yl-&am...

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Main Authors: Ying Guan, Hua-Ru Cao, Yan-Wei Li, Zhen-Jun Si, Lin-Fang Shi
Format: Article
Language:English
Published: International Union of Crystallography 2011-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810052360
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spelling doaj-2319746f7f73415b9dbea945c3e76c682020-11-24T21:26:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m88m8910.1107/S1600536810052360Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvateYing GuanHua-Ru CaoYan-Wei LiZhen-Jun SiLin-Fang ShiIn the title rhenium(I) complex, [ReBr(C13H9N3O)(CO)3]·CH2Cl2, the dichloromethane solvent molecule is disordered over two positions with an occupancy ratio of 0.81 (15):0.19 (15). The ReI atom is coordinated by two N atoms from a 2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole (L) ligand, three C atoms from three carbonyl groups and a Br atom in a distorted octahedral geometry. The three rings in L are almost coplanar (a mean plane fitted through all non-H atoms of this ligand has an r.m.s. deviation of 0.063 Å), and the carbonyl ligands are coordinated in a fac arrangement. http://scripts.iucr.org/cgi-bin/paper?S1600536810052360
collection DOAJ
language English
format Article
sources DOAJ
author Ying Guan
Hua-Ru Cao
Yan-Wei Li
Zhen-Jun Si
Lin-Fang Shi
spellingShingle Ying Guan
Hua-Ru Cao
Yan-Wei Li
Zhen-Jun Si
Lin-Fang Shi
Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate
Acta Crystallographica Section E
author_facet Ying Guan
Hua-Ru Cao
Yan-Wei Li
Zhen-Jun Si
Lin-Fang Shi
author_sort Ying Guan
title Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate
title_short Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate
title_full Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate
title_fullStr Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate
title_full_unstemmed Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate
title_sort bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κn)-1,3,4-oxadiazole-κn4]rhenium(i) dichloromethane monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-01-01
description In the title rhenium(I) complex, [ReBr(C13H9N3O)(CO)3]·CH2Cl2, the dichloromethane solvent molecule is disordered over two positions with an occupancy ratio of 0.81 (15):0.19 (15). The ReI atom is coordinated by two N atoms from a 2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole (L) ligand, three C atoms from three carbonyl groups and a Br atom in a distorted octahedral geometry. The three rings in L are almost coplanar (a mean plane fitted through all non-H atoms of this ligand has an r.m.s. deviation of 0.063 Å), and the carbonyl ligands are coordinated in a fac arrangement.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810052360
work_keys_str_mv AT yingguan bromidotricarbonyl2phenyl5pyridin2ylamp954n134oxadiazoleamp954n4rheniumidichloromethanemonosolvate
AT huarucao bromidotricarbonyl2phenyl5pyridin2ylamp954n134oxadiazoleamp954n4rheniumidichloromethanemonosolvate
AT yanweili bromidotricarbonyl2phenyl5pyridin2ylamp954n134oxadiazoleamp954n4rheniumidichloromethanemonosolvate
AT zhenjunsi bromidotricarbonyl2phenyl5pyridin2ylamp954n134oxadiazoleamp954n4rheniumidichloromethanemonosolvate
AT linfangshi bromidotricarbonyl2phenyl5pyridin2ylamp954n134oxadiazoleamp954n4rheniumidichloromethanemonosolvate
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