Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate
In the title rhenium(I) complex, [ReBr(C13H9N3O)(CO)3]·CH2Cl2, the dichloromethane solvent molecule is disordered over two positions with an occupancy ratio of 0.81 (15):0.19 (15). The ReI atom is coordinated by two N atoms from a 2-phenyl-5-(pyridin-2-yl-&am...
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International Union of Crystallography
2011-01-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810052360 |
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doaj-2319746f7f73415b9dbea945c3e76c682020-11-24T21:26:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m88m8910.1107/S1600536810052360Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvateYing GuanHua-Ru CaoYan-Wei LiZhen-Jun SiLin-Fang ShiIn the title rhenium(I) complex, [ReBr(C13H9N3O)(CO)3]·CH2Cl2, the dichloromethane solvent molecule is disordered over two positions with an occupancy ratio of 0.81 (15):0.19 (15). The ReI atom is coordinated by two N atoms from a 2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole (L) ligand, three C atoms from three carbonyl groups and a Br atom in a distorted octahedral geometry. The three rings in L are almost coplanar (a mean plane fitted through all non-H atoms of this ligand has an r.m.s. deviation of 0.063 Å), and the carbonyl ligands are coordinated in a fac arrangement. http://scripts.iucr.org/cgi-bin/paper?S1600536810052360 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Ying Guan Hua-Ru Cao Yan-Wei Li Zhen-Jun Si Lin-Fang Shi |
spellingShingle |
Ying Guan Hua-Ru Cao Yan-Wei Li Zhen-Jun Si Lin-Fang Shi Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate Acta Crystallographica Section E |
author_facet |
Ying Guan Hua-Ru Cao Yan-Wei Li Zhen-Jun Si Lin-Fang Shi |
author_sort |
Ying Guan |
title |
Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate |
title_short |
Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate |
title_full |
Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate |
title_fullStr |
Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate |
title_full_unstemmed |
Bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole-κN4]rhenium(I) dichloromethane monosolvate |
title_sort |
bromidotricarbonyl[2-phenyl-5-(pyridin-2-yl-κn)-1,3,4-oxadiazole-κn4]rhenium(i) dichloromethane monosolvate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2011-01-01 |
description |
In the title rhenium(I) complex, [ReBr(C13H9N3O)(CO)3]·CH2Cl2, the dichloromethane solvent molecule is disordered over two positions with an occupancy ratio of 0.81 (15):0.19 (15). The ReI atom is coordinated by two N atoms from a 2-phenyl-5-(pyridin-2-yl-κN)-1,3,4-oxadiazole (L) ligand, three C atoms from three carbonyl groups and a Br atom in a distorted octahedral geometry. The three rings in L are almost coplanar (a mean plane fitted through all non-H atoms of this ligand has an r.m.s. deviation of 0.063 Å), and the carbonyl ligands are coordinated in a fac arrangement. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810052360 |
work_keys_str_mv |
AT yingguan bromidotricarbonyl2phenyl5pyridin2ylamp954n134oxadiazoleamp954n4rheniumidichloromethanemonosolvate AT huarucao bromidotricarbonyl2phenyl5pyridin2ylamp954n134oxadiazoleamp954n4rheniumidichloromethanemonosolvate AT yanweili bromidotricarbonyl2phenyl5pyridin2ylamp954n134oxadiazoleamp954n4rheniumidichloromethanemonosolvate AT zhenjunsi bromidotricarbonyl2phenyl5pyridin2ylamp954n134oxadiazoleamp954n4rheniumidichloromethanemonosolvate AT linfangshi bromidotricarbonyl2phenyl5pyridin2ylamp954n134oxadiazoleamp954n4rheniumidichloromethanemonosolvate |
_version_ |
1725979506148114432 |