Bis{bis[2-(diisopropylphosphanyl)phenyl]phosphanido-κ3P,P′,P′′}chloridonickel(II)

Bis{bis[2-(diisopropylphosphanyl)phenyl]phosphanido-κ3P,P′,P′′}chloridonickel(II)

In the title compound, [Ni(C24H36P3)Cl], the NiII atom adopts a distorted square-planar geometry with the two neutral P atoms of the tridentate ligand trans to one another. Bond lengths and angles of the phosphide P atom feature a pyramidal geometry of the donor atom, which forms a single bond with...

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Bibliographic Details
Main Authors: Consiglia Tedesco, Marina Lamberti, Mina Mazzeo
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812044947
Description
Summary:In the title compound, [Ni(C24H36P3)Cl], the NiII atom adopts a distorted square-planar geometry with the two neutral P atoms of the tridentate ligand trans to one another. Bond lengths and angles of the phosphide P atom feature a pyramidal geometry of the donor atom, which forms a single bond with the NiII atom, retaining a stereochemically active lone pair.
ISSN:1600-5368

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