A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides

The synthesis of (diarylmethyl)sulfonamides and related compounds by a new manganese-mediated, cobalt-catalyzed three-component reaction between sulfonamides, carbonyl compounds and organic bromides is described. This organometallic Mannich-like process allows the formation of the coupling products...

Full description

Bibliographic Details
Main Authors:	Antoine Pignon, Erwan Le Gall, Thierry Martens
Format:	Article
Language:	English
Published:	Beilstein-Institut 2014-02-01
Series:	Beilstein Journal of Organic Chemistry
Subjects:	carbonyl compounds cobalt manganese multicomponent reaction organic bromides sulfonamides
Online Access:	https://doi.org/10.3762/bjoc.10.39

id	doaj-2443cbb37e634d2f941d3ce29ee93531
record_format	Article
spelling	doaj-2443cbb37e634d2f941d3ce29ee935312021-04-02T15:33:05ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972014-02-0110142543110.3762/bjoc.10.391860-5397-10-39A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamidesAntoine Pignon0Erwan Le Gall1Thierry Martens2Électrochimie et Synthèse Organique, Institut de Chimie et des Matériaux Paris-Est, UMR 7182 CNRS, Université Paris-Est Créteil, 2-8 rue Henri Dunant, 94320 Thiais, FranceÉlectrochimie et Synthèse Organique, Institut de Chimie et des Matériaux Paris-Est, UMR 7182 CNRS, Université Paris-Est Créteil, 2-8 rue Henri Dunant, 94320 Thiais, FranceÉlectrochimie et Synthèse Organique, Institut de Chimie et des Matériaux Paris-Est, UMR 7182 CNRS, Université Paris-Est Créteil, 2-8 rue Henri Dunant, 94320 Thiais, FranceThe synthesis of (diarylmethyl)sulfonamides and related compounds by a new manganese-mediated, cobalt-catalyzed three-component reaction between sulfonamides, carbonyl compounds and organic bromides is described. This organometallic Mannich-like process allows the formation of the coupling products within minutes at room temperature. A possible mechanism, emphasizing the crucial role of manganese is proposed.https://doi.org/10.3762/bjoc.10.39carbonyl compoundscobaltmanganesemulticomponent reactionorganic bromidessulfonamides
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Antoine Pignon Erwan Le Gall Thierry Martens
spellingShingle	Antoine Pignon Erwan Le Gall Thierry Martens A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides Beilstein Journal of Organic Chemistry carbonyl compounds cobalt manganese multicomponent reaction organic bromides sulfonamides
author_facet	Antoine Pignon Erwan Le Gall Thierry Martens
author_sort	Antoine Pignon
title	A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides
title_short	A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides
title_full	A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides
title_fullStr	A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides
title_full_unstemmed	A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides
title_sort	new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides
publisher	Beilstein-Institut
series	Beilstein Journal of Organic Chemistry
issn	1860-5397
publishDate	2014-02-01
description	The synthesis of (diarylmethyl)sulfonamides and related compounds by a new manganese-mediated, cobalt-catalyzed three-component reaction between sulfonamides, carbonyl compounds and organic bromides is described. This organometallic Mannich-like process allows the formation of the coupling products within minutes at room temperature. A possible mechanism, emphasizing the crucial role of manganese is proposed.
topic	carbonyl compounds cobalt manganese multicomponent reaction organic bromides sulfonamides
url	https://doi.org/10.3762/bjoc.10.39
work_keys_str_mv	AT antoinepignon anewmanganesemediatedcobaltcatalyzedthreecomponentsynthesisofdiarylmethylsulfonamides AT erwanlegall anewmanganesemediatedcobaltcatalyzedthreecomponentsynthesisofdiarylmethylsulfonamides AT thierrymartens anewmanganesemediatedcobaltcatalyzedthreecomponentsynthesisofdiarylmethylsulfonamides AT antoinepignon newmanganesemediatedcobaltcatalyzedthreecomponentsynthesisofdiarylmethylsulfonamides AT erwanlegall newmanganesemediatedcobaltcatalyzedthreecomponentsynthesisofdiarylmethylsulfonamides AT thierrymartens newmanganesemediatedcobaltcatalyzedthreecomponentsynthesisofdiarylmethylsulfonamides
_version_	1721559752722350080

A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides

Similar Items