A Cadmium Anionic 1-D Coordination Polymer {[Cd(H2O)6][Cd2(atr)2(μ2-btc)2(H2O)4] 2H2O}n within a 3-D Supramolecular Charge-Assisted Hydrogen-Bonded and π-Stacking Network

A Cadmium Anionic 1-D Coordination Polymer {[Cd(H2O)6][Cd2(atr)2(μ2-btc)2(H2O)4] 2H2O}n within a 3-D Supramolecular Charge-Assisted Hydrogen-Bonded and π-Stacking Network

The hydrothermal reaction of 4,4′-bis(1,2,4-triazol-4-yl) (btr) and benzene-1,3,5-tricarboxylic acid (H3btc) with Cd(OAc)2·2H2O at 125 °C in situ forms 4-amino-1,2,4-triazole (atr) from btr, which crystallizes to a mixed-ligand, poly-anionic chain of [Cd2(atr)2(µ2-btc)2(H2O)4]2–. Together with a hex...

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Bibliographic Details
Main Authors:	Anas Tahli, Ümit Köc, Reda F. M. Elshaarawy, Anna Christin Kautz, Christoph Janiak
Format:	Article
Language:	English
Published:	MDPI AG 2016-03-01
Series:	Crystals
Subjects:	hydrogen-bonded network anionic coordination polymer crystal engineering charge-assisted H-bonds
Online Access:	http://www.mdpi.com/2073-4352/6/3/23

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