Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15 Ethanol dehydration over LaSBA-15 nanostrutured material
<abstract language="eng">La-incorporated SBA-15 mesopourous molecular sieves (LaSBA-15) were directly synthesized with aim to convert ethanol to ethylene. The samples were characterized by XRD, XRF, nitrogen sorption and acidity, by thermodesorption of n-buthylamine. The results have...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
Sociedade Brasileira de Química
2010-01-01
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Series: | Química Nova |
Subjects: | |
Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000800005 |
Summary: | <abstract language="eng">La-incorporated SBA-15 mesopourous molecular sieves (LaSBA-15) were directly synthesized with aim to convert ethanol to ethylene. The samples were characterized by XRD, XRF, nitrogen sorption and acidity, by thermodesorption of n-buthylamine. The results have indicated that all the samples have showed high ordered mesostructure with a large average pore size, and that the lanthanum incorporation has caused an increase in the acidity of the SBA-15. The LaSBA-15 samples have improved, with low deactivation rate, the conversion of the ethanol to water, ether, acetaldehyde and ethylene. In addition, they have increased the ethylene selectivity. |
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ISSN: | 0100-4042 1678-7064 |