Evidence for single metal two electron oxidative addition and reductive elimination at uranium
The reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within...
Main Authors: | Benedict M. Gardner, Christos E. Kefalidis, Erli Lu, Dipti Patel, Eric J. L. McInnes, Floriana Tuna, Ashley J. Wooles, Laurent Maron, Stephen T. Liddle |
---|---|
Format: | Article |
Language: | English |
Published: |
Nature Publishing Group
2017-12-01
|
Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-017-01363-0 |
Similar Items
-
Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
by: Lucile Chatelain, et al.
Published: (2020-01-01) -
Evidence for ligand- and solvent-induced disproportionation of uranium(IV)
by: Jingzhen Du, et al.
Published: (2021-08-01) -
Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes
by: David M. King, et al.
Published: (2016-12-01) -
Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
by: Ashley J. Wooles, et al.
Published: (2018-05-01) -
On the Dehydrocoupling of Alkenylacetylenes Mediated by Various Samarocene Complexes: A Charming Story of Metal Cooperativity Revealing a Novel Dual Metal σ-Bond Metathesis Type of Mechanism (DM|σ-BM)
by: Christos E. Kefalidis, et al.
Published: (2015-12-01)