Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)

Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)

In the title complex, [PdCl2(C12H8N2)], the Pd2+ ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar molecules, with a maximum deviation of 0.120 (3) ...

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Main Author: Kwang Ha
Format: Article
Language:English
Published: International Union of Crystallography 2010-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809052313
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spelling doaj-2587add7e6454e7eaf44bd7d6979e7e42020-11-24T21:32:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m38m3810.1107/S1600536809052313Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)Kwang HaIn the title complex, [PdCl2(C12H8N2)], the Pd2+ ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar molecules, with a maximum deviation of 0.120 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pd...Pd distance of 4.8340 (9) Å. In the column, π–π interactions between adjacent six-membered rings are present, the shortest centroid–centroid distance being 3.680 (4) Å. A weak C—H...Cl interaction is observed between the columns. http://scripts.iucr.org/cgi-bin/paper?S1600536809052313
collection DOAJ
language English
format Article
sources DOAJ
author Kwang Ha
spellingShingle Kwang Ha
Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)
Acta Crystallographica Section E
author_facet Kwang Ha
author_sort Kwang Ha
title Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)
title_short Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)
title_full Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)
title_fullStr Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)
title_full_unstemmed Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)
title_sort dichlorido(1,10-phenanthroline-κ2n,n′)palladium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-01-01
description In the title complex, [PdCl2(C12H8N2)], the Pd2+ ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar molecules, with a maximum deviation of 0.120 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pd...Pd distance of 4.8340 (9) Å. In the column, π–π interactions between adjacent six-membered rings are present, the shortest centroid–centroid distance being 3.680 (4) Å. A weak C—H...Cl interaction is observed between the columns.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809052313
work_keys_str_mv AT kwangha dichlorido110phenanthrolineamp9542nnamp8242palladiumii
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