Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)
In the title complex, [PdCl2(C12H8N2)], the Pd2+ ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar molecules, with a maximum deviation of 0.120 (3) ...
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International Union of Crystallography
2010-01-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809052313 |
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doaj-2587add7e6454e7eaf44bd7d6979e7e42020-11-24T21:32:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m38m3810.1107/S1600536809052313Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II)Kwang HaIn the title complex, [PdCl2(C12H8N2)], the Pd2+ ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar molecules, with a maximum deviation of 0.120 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pd...Pd distance of 4.8340 (9) Å. In the column, π–π interactions between adjacent six-membered rings are present, the shortest centroid–centroid distance being 3.680 (4) Å. A weak C—H...Cl interaction is observed between the columns. http://scripts.iucr.org/cgi-bin/paper?S1600536809052313 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Kwang Ha |
spellingShingle |
Kwang Ha Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II) Acta Crystallographica Section E |
author_facet |
Kwang Ha |
author_sort |
Kwang Ha |
title |
Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II) |
title_short |
Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II) |
title_full |
Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II) |
title_fullStr |
Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II) |
title_full_unstemmed |
Dichlorido(1,10-phenanthroline-κ2N,N′)palladium(II) |
title_sort |
dichlorido(1,10-phenanthroline-κ2n,n′)palladium(ii) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2010-01-01 |
description |
In the title complex, [PdCl2(C12H8N2)], the Pd2+ ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar molecules, with a maximum deviation of 0.120 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pd...Pd distance of 4.8340 (9) Å. In the column, π–π interactions between adjacent six-membered rings are present, the shortest centroid–centroid distance being 3.680 (4) Å. A weak C—H...Cl interaction is observed between the columns. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809052313 |
work_keys_str_mv |
AT kwangha dichlorido110phenanthrolineamp9542nnamp8242palladiumii |
_version_ |
1725956213285322752 |