Synthesis and diagnosis of a number of new binary zinc complexes with a mixture of lindane (derived from acetyl acetone and semicarbazone) and the study of bio-effectiveness and the effect of laser radiation on them
<br /> Acetylacetoneazineoxime {AAOH}, acetylacetoneazinebis(oxime) {AABOH<sub>2</sub>}, benzilsemicarbazone {BScH} and benzilsemicarbazone hydrazone {BScZH} have been prepared using classical, one pot and microwave heating methods followed by the preparation of new zinc(II) comple...
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doaj-25cac7f08ed741e8a1224365aae64abb2020-11-25T00:26:52ZaraCollege of Education for Pure Sciencesمجلة التربية والعلم1812-125X2664-25302013-12-012658810710.33899/edusj.2013.163092163092Synthesis and diagnosis of a number of new binary zinc complexes with a mixture of lindane (derived from acetyl acetone and semicarbazone) and the study of bio-effectiveness and the effect of laser radiation on themZohoor Al-Tai0Aws Alazi1Department of Chemistry, College of Education, Mosul UniversityDepartment of Chemistry, College of Education, Mosul University<br /> Acetylacetoneazineoxime {AAOH}, acetylacetoneazinebis(oxime) {AABOH<sub>2</sub>}, benzilsemicarbazone {BScH} and benzilsemicarbazone hydrazone {BScZH} have been prepared using classical, one pot and microwave heating methods followed by the preparation of new zinc(II) complexes in neutral (or slightly acidic) medium with mixed ligands above using classical and microwave heating (Green Chemistry) methods. The resulting complexes have been characterized using elemental analysis by atomic absorption spectroscopy and CHN analysis, relative molecular weight determination cryoscopically, molar conductance measurements, infrared, electronic and <sup>1</sup>H NMR spectra. The study suggests that the above ligands form neutral complexes having general formulas [Zn(AH)(BH)(CH<sub>3</sub>COO)<sub>2</sub>] (where AH = AAOH or AABOH<sub>2;</sub> BH=BScH or BScZH ligands). Accordingly, hexa-coordinated mononuclear complexes have been investigated having distorted octahedral geometries.<br /> The effect of laser have been studied on solid ligands and solid zinc(II) complexes, no effect have been observed on all the compounds through the results of melting point and conductivity, this means that most of the compounds are stable and not affected by this kind of radiation. Also the activity of all the complexes have been evaluated on Tonsillitis from males and Females. They were found to be unactive against this pathogens.https://edusj.mosuljournals.com/article_163092_b7c09cd7710726ecc272d364654a5f5e.pdfsynthesisbinary zinc complexesmixture of lindaneacetyl acetonesemicarbazone |
collection |
DOAJ |
language |
Arabic |
format |
Article |
sources |
DOAJ |
author |
Zohoor Al-Tai Aws Alazi |
spellingShingle |
Zohoor Al-Tai Aws Alazi Synthesis and diagnosis of a number of new binary zinc complexes with a mixture of lindane (derived from acetyl acetone and semicarbazone) and the study of bio-effectiveness and the effect of laser radiation on them مجلة التربية والعلم synthesis binary zinc complexes mixture of lindane acetyl acetone semicarbazone |
author_facet |
Zohoor Al-Tai Aws Alazi |
author_sort |
Zohoor Al-Tai |
title |
Synthesis and diagnosis of a number of new binary zinc complexes with a mixture of lindane (derived from acetyl acetone and semicarbazone) and the study of bio-effectiveness and the effect of laser radiation on them |
title_short |
Synthesis and diagnosis of a number of new binary zinc complexes with a mixture of lindane (derived from acetyl acetone and semicarbazone) and the study of bio-effectiveness and the effect of laser radiation on them |
title_full |
Synthesis and diagnosis of a number of new binary zinc complexes with a mixture of lindane (derived from acetyl acetone and semicarbazone) and the study of bio-effectiveness and the effect of laser radiation on them |
title_fullStr |
Synthesis and diagnosis of a number of new binary zinc complexes with a mixture of lindane (derived from acetyl acetone and semicarbazone) and the study of bio-effectiveness and the effect of laser radiation on them |
title_full_unstemmed |
Synthesis and diagnosis of a number of new binary zinc complexes with a mixture of lindane (derived from acetyl acetone and semicarbazone) and the study of bio-effectiveness and the effect of laser radiation on them |
title_sort |
synthesis and diagnosis of a number of new binary zinc complexes with a mixture of lindane (derived from acetyl acetone and semicarbazone) and the study of bio-effectiveness and the effect of laser radiation on them |
publisher |
College of Education for Pure Sciences |
series |
مجلة التربية والعلم |
issn |
1812-125X 2664-2530 |
publishDate |
2013-12-01 |
description |
<br /> Acetylacetoneazineoxime {AAOH}, acetylacetoneazinebis(oxime) {AABOH<sub>2</sub>}, benzilsemicarbazone {BScH} and benzilsemicarbazone hydrazone {BScZH} have been prepared using classical, one pot and microwave heating methods followed by the preparation of new zinc(II) complexes in neutral (or slightly acidic) medium with mixed ligands above using classical and microwave heating (Green Chemistry) methods. The resulting complexes have been characterized using elemental analysis by atomic absorption spectroscopy and CHN analysis, relative molecular weight determination cryoscopically, molar conductance measurements, infrared, electronic and <sup>1</sup>H NMR spectra. The study suggests that the above ligands form neutral complexes having general formulas [Zn(AH)(BH)(CH<sub>3</sub>COO)<sub>2</sub>] (where AH = AAOH or AABOH<sub>2;</sub> BH=BScH or BScZH ligands). Accordingly, hexa-coordinated mononuclear complexes have been investigated having distorted octahedral geometries.<br /> The effect of laser have been studied on solid ligands and solid zinc(II) complexes, no effect have been observed on all the compounds through the results of melting point and conductivity, this means that most of the compounds are stable and not affected by this kind of radiation. Also the activity of all the complexes have been evaluated on Tonsillitis from males and Females. They were found to be unactive against this pathogens. |
topic |
synthesis binary zinc complexes mixture of lindane acetyl acetone semicarbazone |
url |
https://edusj.mosuljournals.com/article_163092_b7c09cd7710726ecc272d364654a5f5e.pdf |
work_keys_str_mv |
AT zohooraltai synthesisanddiagnosisofanumberofnewbinaryzinccomplexeswithamixtureoflindanederivedfromacetylacetoneandsemicarbazoneandthestudyofbioeffectivenessandtheeffectoflaserradiationonthem AT awsalazi synthesisanddiagnosisofanumberofnewbinaryzinccomplexeswithamixtureoflindanederivedfromacetylacetoneandsemicarbazoneandthestudyofbioeffectivenessandtheeffectoflaserradiationonthem |
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