Preparation of ZrO2/Al2O3-montmorillonite composite as catalyst for phenol hydroxylation
Zirconium dispersed in aluminum-pillared montmorillonite was prepared as a catalyst for phenol hydroxylation. The effects of varying the Zr content on the catalyst’s physicochemical character and activity were studied with XRD, BET surface area analysis, surface acidity measurements and scanning el...
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doaj-26692c4bddfd4a5b8c6d5321bec583902020-11-24T20:51:02ZengElsevierJournal of Advanced Research2090-12322014-11-015666367010.1016/j.jare.2013.10.003Preparation of ZrO2/Al2O3-montmorillonite composite as catalyst for phenol hydroxylationIs Fatimah Zirconium dispersed in aluminum-pillared montmorillonite was prepared as a catalyst for phenol hydroxylation. The effects of varying the Zr content on the catalyst’s physicochemical character and activity were studied with XRD, BET surface area analysis, surface acidity measurements and scanning electron microscopy before investigating the performance for phenol conversion. The zirconia dispersion significantly affects the specific surface area, the total surface acidity and surface acidity distribution related to the formation of porous zirconia particles on the surface. The prepared samples exhibited excellent catalytic activity during phenol hydroxylation. http://www.sciencedirect.com/science/article/pii/S2090123213001355Pillared clayPhenolHydroxylationZirconiaCatalysis |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Is Fatimah |
spellingShingle |
Is Fatimah Preparation of ZrO2/Al2O3-montmorillonite composite as catalyst for phenol hydroxylation Journal of Advanced Research Pillared clay Phenol Hydroxylation Zirconia Catalysis |
author_facet |
Is Fatimah |
author_sort |
Is Fatimah |
title |
Preparation of ZrO2/Al2O3-montmorillonite composite as catalyst for phenol hydroxylation |
title_short |
Preparation of ZrO2/Al2O3-montmorillonite composite as catalyst for phenol hydroxylation |
title_full |
Preparation of ZrO2/Al2O3-montmorillonite composite as catalyst for phenol hydroxylation |
title_fullStr |
Preparation of ZrO2/Al2O3-montmorillonite composite as catalyst for phenol hydroxylation |
title_full_unstemmed |
Preparation of ZrO2/Al2O3-montmorillonite composite as catalyst for phenol hydroxylation |
title_sort |
preparation of zro2/al2o3-montmorillonite composite as catalyst for phenol hydroxylation |
publisher |
Elsevier |
series |
Journal of Advanced Research |
issn |
2090-1232 |
publishDate |
2014-11-01 |
description |
Zirconium dispersed in aluminum-pillared montmorillonite was prepared as a catalyst for phenol hydroxylation. The effects of varying the Zr content on the catalyst’s physicochemical character and activity were studied with XRD, BET surface area analysis, surface acidity measurements and scanning electron microscopy before investigating the performance for phenol conversion. The zirconia dispersion significantly affects the specific surface area, the total surface acidity and surface acidity distribution related to the formation of porous zirconia particles on the surface. The prepared samples exhibited excellent catalytic activity during phenol hydroxylation.
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topic |
Pillared clay Phenol Hydroxylation Zirconia Catalysis |
url |
http://www.sciencedirect.com/science/article/pii/S2090123213001355 |
work_keys_str_mv |
AT isfatimah preparationofzro2al2o3montmorillonitecompositeascatalystforphenolhydroxylation |
_version_ |
1716802945358495744 |