| Summary: | In the title hydrated salt, 2,4,6-triamino-1,3,5-triazin-1-ium perchlorate monohydrate, C3H7N6+·ClO4−·H2O, the constituents are linked via hydrogen bonds of the O—H...O, N—H...O, N—H...N and N—H...Cl types. All the H atoms of the melaminium cation are involved in the hydrogen bonds. The melaminium residues are interconnected by four N—H...N hydrogen bonds, forming chains parallel to (111). The ribbons are interconnected by other hydrogen bonds as well as by π–π interactions [centroid–centroid distance = 3.8097 (7) Å].
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