Nitrogen Adsorption on Molecular Sieve Zeolites: An Experimental and Modeling Study
Separation of nitrogen from a gaseous mixture is required for many industrial processes. In this study, the adsorption of nitrogen on zeolite 4A was investigated in terms of different adsorption isotherm models and kinetics. An increase in the initial pressure from 1 to 9 bar increases the amount of...
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doaj-276d58e2f7094b049d62c874f21d9c932020-11-25T04:12:05ZengPetroleum University of TechnologyIranian Journal of Oil & Gas Science and Technology2345-24122345-24202020-01-0191476710.22050/ijogst.2019.186102.1506105518Nitrogen Adsorption on Molecular Sieve Zeolites: An Experimental and Modeling StudyErfan Tooraji0Ahad Ghaemi1M.S. Student, School of Chemical, Petroleum, and Gas Engineering, Iran University of Science and Technology, P.O. Box 16846-13114, Tehran, IranAssociate Professor, School of Chemical, Petroleum, and Gas Engineering, Iran University of Science and Technology, P.O. Box 16846-13114, Tehran, IranSeparation of nitrogen from a gaseous mixture is required for many industrial processes. In this study, the adsorption of nitrogen on zeolite 4A was investigated in terms of different adsorption isotherm models and kinetics. An increase in the initial pressure from 1 to 9 bar increases the amount of adsorbed nitrogen from 6.730 to 376.030 mg/(g adsorbent). The amount of adsorbed nitrogen increased from 7.321 to 40.594 mg/(g adsorbent) by raising the temperature from 298 to 333 K at a pressure equal to one bar; however, it then dropped to 15.767 mg/(g adsorbent) when temperature decreased to 353 K. Increasing the amount of the adsorbent from 1 to 4 g decreased the specific adsorption from 67.565 to 21.008 mg/(g adsorbent) at a temperature of 298 K and a pressure of 3 bar. Furthermore, it was found that the nitrogen adsorption experimental equilibrium data are consistent with Sips and Langmuir-Freundlich models. The highest overlap was achieved through second order and Ritchie’s models.http://ijogst.put.ac.ir/article_105518_7ea7dea3f744463b813b1bfac6d135e3.pdfadsorptionnitrogenmolecular sieveisothermkinetics |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Erfan Tooraji Ahad Ghaemi |
spellingShingle |
Erfan Tooraji Ahad Ghaemi Nitrogen Adsorption on Molecular Sieve Zeolites: An Experimental and Modeling Study Iranian Journal of Oil & Gas Science and Technology adsorption nitrogen molecular sieve isotherm kinetics |
author_facet |
Erfan Tooraji Ahad Ghaemi |
author_sort |
Erfan Tooraji |
title |
Nitrogen Adsorption on Molecular Sieve Zeolites: An Experimental and Modeling Study |
title_short |
Nitrogen Adsorption on Molecular Sieve Zeolites: An Experimental and Modeling Study |
title_full |
Nitrogen Adsorption on Molecular Sieve Zeolites: An Experimental and Modeling Study |
title_fullStr |
Nitrogen Adsorption on Molecular Sieve Zeolites: An Experimental and Modeling Study |
title_full_unstemmed |
Nitrogen Adsorption on Molecular Sieve Zeolites: An Experimental and Modeling Study |
title_sort |
nitrogen adsorption on molecular sieve zeolites: an experimental and modeling study |
publisher |
Petroleum University of Technology |
series |
Iranian Journal of Oil & Gas Science and Technology |
issn |
2345-2412 2345-2420 |
publishDate |
2020-01-01 |
description |
Separation of nitrogen from a gaseous mixture is required for many industrial processes. In this study, the adsorption of nitrogen on zeolite 4A was investigated in terms of different adsorption isotherm models and kinetics. An increase in the initial pressure from 1 to 9 bar increases the amount of adsorbed nitrogen from 6.730 to 376.030 mg/(g adsorbent). The amount of adsorbed nitrogen increased from 7.321 to 40.594 mg/(g adsorbent) by raising the temperature from 298 to 333 K at a pressure equal to one bar; however, it then dropped to 15.767 mg/(g adsorbent) when temperature decreased to 353 K. Increasing the amount of the adsorbent from 1 to 4 g decreased the specific adsorption from 67.565 to 21.008 mg/(g adsorbent) at a temperature of 298 K and a pressure of 3 bar. Furthermore, it was found that the nitrogen adsorption experimental equilibrium data are consistent with Sips and Langmuir-Freundlich models. The highest overlap was achieved through second order and Ritchie’s models. |
topic |
adsorption nitrogen molecular sieve isotherm kinetics |
url |
http://ijogst.put.ac.ir/article_105518_7ea7dea3f744463b813b1bfac6d135e3.pdf |
work_keys_str_mv |
AT erfantooraji nitrogenadsorptiononmolecularsievezeolitesanexperimentalandmodelingstudy AT ahadghaemi nitrogenadsorptiononmolecularsievezeolitesanexperimentalandmodelingstudy |
_version_ |
1724416105377693696 |