SEPARATION OF p-AMINOBENZOIC ACID BY REACTIVE EXTRACTION. 1. MECHANISM AND INFLUENCING FACTORS

• Main Authors: DAN CASCAVAL, MARIA CAMARUT, ANCA-IRINA GALACTION
• Format: Article
• Language: English
• Published: Association of the Chemical Engineers of Serbia 2008-09-01
• Series: Chemical Industry and Chemical Engineering Quarterly
• Subjects: p-aminobenzoic acid; reactive extraction; Amberlite LA-2; di-(2-ethylhexyl) phosphoric acid; extraction constant; distribution coefficient
• Online Access: http://www.ache.org.rs/CICEQ/2008/No3/02_14%283%29_2008.pdf

The comparative study on the reactive extraction of p-aminobenzoic acid with Amberlite LA-2 and D2EHPA in two solvents with different polarity (n-heptane and dichloromethane) indicated that the extractant type and solvent polarity control the extraction mechanism. Thus, the reactive extraction with Amberlite LA-2 occurs by means of the interfacial formation of an aminic adduct with three extractant molecules in low-polar solvent, or of an salt with one extractant molecule in higher polar solvent. Similarly, the extraction with D2EHPA is based on the formation of an acidic adduct with two extractant molecules in n-heptane, or of a salt with one extractant molecule in dichloromethane. The most efficient extraction has been reached for the combination Amberlite LA-2-dichloromethane.