ADMET Polymerization of Dimeric Cinchona Squaramides for the Preparation of a Highly Enantioselective Polymeric Organocatalyst

ADMET Polymerization of Dimeric Cinchona Squaramides for the Preparation of a Highly Enantioselective Polymeric Organocatalyst

Under the acyclic diene metathesis (ADMET) reaction condition, the C3-vinyl groups of cinchona alkaloids readily react with each other to form a C-C bond. A novel type of cinchona alkaloid polymers was synthesized from dimeric cinchona squaramides using the Hoveyda-Grubbs’ second-generation catalyst...

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Bibliographic Details
Main Authors: Mohammad Shahid Ullah, Sadia Afrin Chhanda, Shinichi Itsuno
Format: Article
Language:English
Published: MDPI AG 2020-05-01
Series:Catalysts
Subjects:
ADMET
cinchona alkaloid
squaramide
polymeric organocatalyst
Michael addition
pseudoenantiomer
Online Access:https://www.mdpi.com/2073-4344/10/5/591

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