Poly[(acetato-κ2O,O′)aqua(μ4-1H-benzimidazole-5,6-dicarboxylato-κ5N3:O5,O5′:O5,O6:O6′)praseodymium(III)]

Poly[(acetato-κ2O,O′)aqua(μ4-1H-benzimidazole-5,6-dicarboxylato-κ5N3:O5,O5′:O5,O6:O6′)praseodymium(III)]

In the title complex, [Pr(C9H4N2O4)(C2H3O2)(H2O)]n, the PrIII ion is coordinated by five O atoms and one N atom from four benzimidazole-5,6-dicarboxylate ligands, two O atoms from an acetate ligand and one water molecule, giving a tricapped trigonal-prismatic geometry. The benzimidazole-5,6-dicarbox...

Full description

Bibliographic Details
Main Authors: Yi-Fan Luo, Xuan Xu, Jian-Fen Lin, Jin-Hua Chen, Zi-Yu Pan
Format: Article
Language:English
Published: International Union of Crystallography 2010-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810036986
id doaj-288e54d60f7149cab1c26964e73dca09
record_format Article
spelling doaj-288e54d60f7149cab1c26964e73dca092020-11-25T02:19:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1302m130210.1107/S1600536810036986Poly[(acetato-κ2O,O′)aqua(μ4-1H-benzimidazole-5,6-dicarboxylato-κ5N3:O5,O5′:O5,O6:O6′)praseodymium(III)]Yi-Fan LuoXuan XuJian-Fen LinJin-Hua ChenZi-Yu PanIn the title complex, [Pr(C9H4N2O4)(C2H3O2)(H2O)]n, the PrIII ion is coordinated by five O atoms and one N atom from four benzimidazole-5,6-dicarboxylate ligands, two O atoms from an acetate ligand and one water molecule, giving a tricapped trigonal-prismatic geometry. The benzimidazole-5,6-dicarboxylate and acetate ligands connect the PrIII ions, forming a layer in the ac plane; the layers are further linked by N—H...O and O—H...O hydrogen bonding and π–π stacking interactions between neighboring pyridine rings [the centroid–centroid distance is 3.467 (1) Å], assembling a three-dimensional supramolecular network. The acetate methyl group is disordered over two positions with site-occupancy factors of 0.75 and 0.25. http://scripts.iucr.org/cgi-bin/paper?S1600536810036986
collection DOAJ
language English
format Article
sources DOAJ
author Yi-Fan Luo
Xuan Xu
Jian-Fen Lin
Jin-Hua Chen
Zi-Yu Pan
spellingShingle Yi-Fan Luo
Xuan Xu
Jian-Fen Lin
Jin-Hua Chen
Zi-Yu Pan
Poly[(acetato-κ2O,O′)aqua(μ4-1H-benzimidazole-5,6-dicarboxylato-κ5N3:O5,O5′:O5,O6:O6′)praseodymium(III)]
Acta Crystallographica Section E
author_facet Yi-Fan Luo
Xuan Xu
Jian-Fen Lin
Jin-Hua Chen
Zi-Yu Pan
author_sort Yi-Fan Luo
title Poly[(acetato-κ2O,O′)aqua(μ4-1H-benzimidazole-5,6-dicarboxylato-κ5N3:O5,O5′:O5,O6:O6′)praseodymium(III)]
title_short Poly[(acetato-κ2O,O′)aqua(μ4-1H-benzimidazole-5,6-dicarboxylato-κ5N3:O5,O5′:O5,O6:O6′)praseodymium(III)]
title_full Poly[(acetato-κ2O,O′)aqua(μ4-1H-benzimidazole-5,6-dicarboxylato-κ5N3:O5,O5′:O5,O6:O6′)praseodymium(III)]
title_fullStr Poly[(acetato-κ2O,O′)aqua(μ4-1H-benzimidazole-5,6-dicarboxylato-κ5N3:O5,O5′:O5,O6:O6′)praseodymium(III)]
title_full_unstemmed Poly[(acetato-κ2O,O′)aqua(μ4-1H-benzimidazole-5,6-dicarboxylato-κ5N3:O5,O5′:O5,O6:O6′)praseodymium(III)]
title_sort poly[(acetato-κ2o,o′)aqua(μ4-1h-benzimidazole-5,6-dicarboxylato-κ5n3:o5,o5′:o5,o6:o6′)praseodymium(iii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-10-01
description In the title complex, [Pr(C9H4N2O4)(C2H3O2)(H2O)]n, the PrIII ion is coordinated by five O atoms and one N atom from four benzimidazole-5,6-dicarboxylate ligands, two O atoms from an acetate ligand and one water molecule, giving a tricapped trigonal-prismatic geometry. The benzimidazole-5,6-dicarboxylate and acetate ligands connect the PrIII ions, forming a layer in the ac plane; the layers are further linked by N—H...O and O—H...O hydrogen bonding and π–π stacking interactions between neighboring pyridine rings [the centroid–centroid distance is 3.467 (1) Å], assembling a three-dimensional supramolecular network. The acetate methyl group is disordered over two positions with site-occupancy factors of 0.75 and 0.25.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810036986
work_keys_str_mv AT yifanluo polyacetatoamp9542ooamp8242aquaamp95641hbenzimidazole56dicarboxylatoamp9545n3o5o5amp8242o5o6o6amp8242praseodymiumiii
AT xuanxu polyacetatoamp9542ooamp8242aquaamp95641hbenzimidazole56dicarboxylatoamp9545n3o5o5amp8242o5o6o6amp8242praseodymiumiii
AT jianfenlin polyacetatoamp9542ooamp8242aquaamp95641hbenzimidazole56dicarboxylatoamp9545n3o5o5amp8242o5o6o6amp8242praseodymiumiii
AT jinhuachen polyacetatoamp9542ooamp8242aquaamp95641hbenzimidazole56dicarboxylatoamp9545n3o5o5amp8242o5o6o6amp8242praseodymiumiii
AT ziyupan polyacetatoamp9542ooamp8242aquaamp95641hbenzimidazole56dicarboxylatoamp9545n3o5o5amp8242o5o6o6amp8242praseodymiumiii
_version_ 1724877704875999232

Similar Items