2,3,5-Triphenyl-2H-tetrazol-3-ium iodide
The asymmetric unit of the title molecular salt, C19H15N4+·I−, contains four 2,3,5-triphenyl-2H-tetrazol-3-ium cations and five iodide anions, with two of the latter lying on crystallographic inversion centres. In each cation, the tetrazole ring is essentially planar (r.m....
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| Language: | English |
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International Union of Crystallography
2012-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812033661 |
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doaj-28b1e8aec51f449a97767fc041dc0bcf2020-11-25T01:35:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689o2621o262110.1107/S16005368120336612,3,5-Triphenyl-2H-tetrazol-3-ium iodideHoong-Kun FunTze Shyang ChiaGamal A. E. MostafaMohamed M. AbunassifHatem A. Abdel-AzizThe asymmetric unit of the title molecular salt, C19H15N4+·I−, contains four 2,3,5-triphenyl-2H-tetrazol-3-ium cations and five iodide anions, with two of the latter lying on crystallographic inversion centres. In each cation, the tetrazole ring is essentially planar (r.m.s. deviations = 0.004–0.007 Å). The dihedral angles between the tetrazole ring and its three attached benzene rings in the four independent cations are: 12.9 (4), 67.0 (4), 48.1 (4); 20.8 (4), 51.1 (4), 62.3 (4); 11.4 (4), 52.3 (4), 47.3 (4) and 6.0 (4), 85.7 (4), 43.5 (4)°. A C—H...I hydrogen bond and C—H...π interactions are observed in the crystal.http://scripts.iucr.org/cgi-bin/paper?S1600536812033661 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Hoong-Kun Fun Tze Shyang Chia Gamal A. E. Mostafa Mohamed M. Abunassif Hatem A. Abdel-Aziz |
| spellingShingle |
Hoong-Kun Fun Tze Shyang Chia Gamal A. E. Mostafa Mohamed M. Abunassif Hatem A. Abdel-Aziz 2,3,5-Triphenyl-2H-tetrazol-3-ium iodide Acta Crystallographica Section E |
| author_facet |
Hoong-Kun Fun Tze Shyang Chia Gamal A. E. Mostafa Mohamed M. Abunassif Hatem A. Abdel-Aziz |
| author_sort |
Hoong-Kun Fun |
| title |
2,3,5-Triphenyl-2H-tetrazol-3-ium iodide |
| title_short |
2,3,5-Triphenyl-2H-tetrazol-3-ium iodide |
| title_full |
2,3,5-Triphenyl-2H-tetrazol-3-ium iodide |
| title_fullStr |
2,3,5-Triphenyl-2H-tetrazol-3-ium iodide |
| title_full_unstemmed |
2,3,5-Triphenyl-2H-tetrazol-3-ium iodide |
| title_sort |
2,3,5-triphenyl-2h-tetrazol-3-ium iodide |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-09-01 |
| description |
The asymmetric unit of the title molecular salt, C19H15N4+·I−, contains four 2,3,5-triphenyl-2H-tetrazol-3-ium cations and five iodide anions, with two of the latter lying on crystallographic inversion centres. In each cation, the tetrazole ring is essentially planar (r.m.s. deviations = 0.004–0.007 Å). The dihedral angles between the tetrazole ring and its three attached benzene rings in the four independent cations are: 12.9 (4), 67.0 (4), 48.1 (4); 20.8 (4), 51.1 (4), 62.3 (4); 11.4 (4), 52.3 (4), 47.3 (4) and 6.0 (4), 85.7 (4), 43.5 (4)°. A C—H...I hydrogen bond and C—H...π interactions are observed in the crystal. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812033661 |
| work_keys_str_mv |
AT hoongkunfun 235triphenyl2htetrazol3iumiodide AT tzeshyangchia 235triphenyl2htetrazol3iumiodide AT gamalaemostafa 235triphenyl2htetrazol3iumiodide AT mohamedmabunassif 235triphenyl2htetrazol3iumiodide AT hatemaabdelaziz 235triphenyl2htetrazol3iumiodide |
| _version_ |
1725066929639522304 |