Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)

Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)

The title compound, [Co(C4H13N3)2][InCl6], was synthesized under hydrothermal conditions. In the cation, the Co—N bond lengths lie in the range 1.967 (2)–1.9684 (15) Å. In the anion, the InIII atom is coordinated by s...

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Main Authors: Qihui Wu, Shangwen Chen, Cailing Zhang, Xia Zhi, Zelin Chen
Format: Article
Language:English
Published: International Union of Crystallography 2011-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811016758
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spelling doaj-28e6197341aa43709f79d67d82587ff32020-11-25T02:40:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m731m73110.1107/S1600536811016758Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)Qihui WuShangwen ChenCailing ZhangXia ZhiZelin ChenThe title compound, [Co(C4H13N3)2][InCl6], was synthesized under hydrothermal conditions. In the cation, the Co—N bond lengths lie in the range 1.967 (2)–1.9684 (15) Å. In the anion, the InIII atom is coordinated by six Cl atoms resulting in a slightly distorted octahedral geometry. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one Cl atom and one N atom are located on a mirror plane. N—H...Cl hydrogen bonds between cations and anions consolidate the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536811016758
collection DOAJ
language English
format Article
sources DOAJ
author Qihui Wu
Shangwen Chen
Cailing Zhang
Xia Zhi
Zelin Chen
spellingShingle Qihui Wu
Shangwen Chen
Cailing Zhang
Xia Zhi
Zelin Chen
Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)
Acta Crystallographica Section E
author_facet Qihui Wu
Shangwen Chen
Cailing Zhang
Xia Zhi
Zelin Chen
author_sort Qihui Wu
title Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)
title_short Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)
title_full Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)
title_fullStr Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)
title_full_unstemmed Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)
title_sort bis(diethylenetriamine)cobalt(iii) hexachloridoindate(iii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-06-01
description The title compound, [Co(C4H13N3)2][InCl6], was synthesized under hydrothermal conditions. In the cation, the Co—N bond lengths lie in the range 1.967 (2)–1.9684 (15) Å. In the anion, the InIII atom is coordinated by six Cl atoms resulting in a slightly distorted octahedral geometry. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one Cl atom and one N atom are located on a mirror plane. N—H...Cl hydrogen bonds between cations and anions consolidate the crystal packing.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811016758
work_keys_str_mv AT qihuiwu bisdiethylenetriaminecobaltiiihexachloridoindateiii
AT shangwenchen bisdiethylenetriaminecobaltiiihexachloridoindateiii
AT cailingzhang bisdiethylenetriaminecobaltiiihexachloridoindateiii
AT xiazhi bisdiethylenetriaminecobaltiiihexachloridoindateiii
AT zelinchen bisdiethylenetriaminecobaltiiihexachloridoindateiii
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