Dichlorido(2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate)cadmium(II)

Dichlorido(2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate)cadmium(II)

In the title compound, [CdCl2(C13H19N3O)], the CdII ion is pentacoordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the c...

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Main Authors: Muhammad Saleh Salga, Hamid Khaledi, Hapipah Mohd Ali
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810032563
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spelling doaj-29a5bff91cca4cfdbeeca5b11deb2ca52020-11-24T21:53:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1131m113110.1107/S1600536810032563Dichlorido(2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate)cadmium(II)Muhammad Saleh SalgaHamid KhalediHapipah Mohd AliIn the title compound, [CdCl2(C13H19N3O)], the CdII ion is pentacoordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the crystal structure, adjacent molecules are linked together via N—H...O and N—H...Cl hydrogen bonds, forming infinite layers parallel to the ab plane. The layers are further connected through C—H...Cl interactions into a three-dimensional network. http://scripts.iucr.org/cgi-bin/paper?S1600536810032563
collection DOAJ
language English
format Article
sources DOAJ
author Muhammad Saleh Salga
Hamid Khaledi
Hapipah Mohd Ali
spellingShingle Muhammad Saleh Salga
Hamid Khaledi
Hapipah Mohd Ali
Dichlorido(2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate)cadmium(II)
Acta Crystallographica Section E
author_facet Muhammad Saleh Salga
Hamid Khaledi
Hapipah Mohd Ali
author_sort Muhammad Saleh Salga
title Dichlorido(2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate)cadmium(II)
title_short Dichlorido(2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate)cadmium(II)
title_full Dichlorido(2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate)cadmium(II)
title_fullStr Dichlorido(2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate)cadmium(II)
title_full_unstemmed Dichlorido(2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate)cadmium(II)
title_sort dichlorido(2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate)cadmium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-09-01
description In the title compound, [CdCl2(C13H19N3O)], the CdII ion is pentacoordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)ethyl]iminomethyl}phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the crystal structure, adjacent molecules are linked together via N—H...O and N—H...Cl hydrogen bonds, forming infinite layers parallel to the ab plane. The layers are further connected through C—H...Cl interactions into a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810032563
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AT hamidkhaledi dichlorido22piperazin4ium1ylethyliminomethylphenolatecadmiumii
AT hapipahmohdali dichlorido22piperazin4ium1ylethyliminomethylphenolatecadmiumii
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