Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(II)] monohydrate]

Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(II)] monohydrate]

In the crystal structure of the title compound, {[Cd(C2Cl3O2)2(C12H10N2)2]·H2O}n, the CdII ion lies on a twofold rotation axis and 1,2-bis(4-pyridyl)ethene ligands bridge symmetry-related CdII ions, forming a two-dimensional structure. Two trichloroacetate ligands complete the coordinat...

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Main Authors: Youngmee Kim, Cheal Kim, Jin Hoon Kim
Format: Article
Language:English
Published: International Union of Crystallography 2011-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810049457
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spelling doaj-2ad8f0996ccf4d88ba416bddd8c41f412020-11-25T01:50:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m3m410.1107/S1600536810049457Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(II)] monohydrate]Youngmee KimCheal KimJin Hoon KimIn the crystal structure of the title compound, {[Cd(C2Cl3O2)2(C12H10N2)2]·H2O}n, the CdII ion lies on a twofold rotation axis and 1,2-bis(4-pyridyl)ethene ligands bridge symmetry-related CdII ions, forming a two-dimensional structure. Two trichloroacetate ligands complete the coordination around the CdII ion, forming a distorted octahedral environment. In the crystal, solvent water molecules, which also lie on twofold rotation axes, form intermolecular O—H...O hydrogen bonds, which connect the two-dimensional structure into a three-dimensional network. The crystal studied was an inversion twin, the refined ratio of twin components being 0.75 (4):0.25 (4). http://scripts.iucr.org/cgi-bin/paper?S1600536810049457
collection DOAJ
language English
format Article
sources DOAJ
author Youngmee Kim
Cheal Kim
Jin Hoon Kim
spellingShingle Youngmee Kim
Cheal Kim
Jin Hoon Kim
Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(II)] monohydrate]
Acta Crystallographica Section E
author_facet Youngmee Kim
Cheal Kim
Jin Hoon Kim
author_sort Youngmee Kim
title Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(II)] monohydrate]
title_short Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(II)] monohydrate]
title_full Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(II)] monohydrate]
title_fullStr Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(II)] monohydrate]
title_full_unstemmed Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(II)] monohydrate]
title_sort poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(ii)] monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-01-01
description In the crystal structure of the title compound, {[Cd(C2Cl3O2)2(C12H10N2)2]·H2O}n, the CdII ion lies on a twofold rotation axis and 1,2-bis(4-pyridyl)ethene ligands bridge symmetry-related CdII ions, forming a two-dimensional structure. Two trichloroacetate ligands complete the coordination around the CdII ion, forming a distorted octahedral environment. In the crystal, solvent water molecules, which also lie on twofold rotation axes, form intermolecular O—H...O hydrogen bonds, which connect the two-dimensional structure into a three-dimensional network. The crystal studied was an inversion twin, the refined ratio of twin components being 0.75 (4):0.25 (4).
url http://scripts.iucr.org/cgi-bin/paper?S1600536810049457
work_keys_str_mv AT youngmeekim polybisamp95612bis4pyridylethenebistrichloroacetatocadmiumiimonohydrate
AT chealkim polybisamp95612bis4pyridylethenebistrichloroacetatocadmiumiimonohydrate
AT jinhoonkim polybisamp95612bis4pyridylethenebistrichloroacetatocadmiumiimonohydrate
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