Formation of Hydrogen-Ion in Isomolar Solution of Hydrochloric and Hydrobromic Acids and Their Salts
Despite the presence of a large amount of factual material on thermodynamic parameters of complexation of agents in different solvents, including mixed ones, obtained knowledge is specific in nature. In order to identify more general patterns, studies are relevant that would allow to interpret the o...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Kazan Federal University
2016-09-01
|
Series: | Učënye Zapiski Kazanskogo Universiteta. Seriâ Estestvennye Nauki |
Subjects: | |
Online Access: | http://kpfu.ru/portal/docs/F1646893366/158_3_est_5.pdf |
id |
doaj-2b009109e9be4c538dd2240c2694bf55 |
---|---|
record_format |
Article |
spelling |
doaj-2b009109e9be4c538dd2240c2694bf552020-11-24T23:58:43ZengKazan Federal UniversityUčënye Zapiski Kazanskogo Universiteta. Seriâ Estestvennye Nauki1815-61692500-218X2016-09-011583381390Formation of Hydrogen-Ion in Isomolar Solution of Hydrochloric and Hydrobromic Acids and Their SaltsM.A. Kovaleva0V.A. Fedorov1V.A. Ganja2Siberian Federal University, Krasnoyarsk, 660041 RussiaSiberian State Technological University, Krasnoyarsk, 660049 RussiaSiberian Federal University, Krasnoyarsk, 660041 RussiaDespite the presence of a large amount of factual material on thermodynamic parameters of complexation of agents in different solvents, including mixed ones, obtained knowledge is specific in nature. In order to identify more general patterns, studies are relevant that would allow to interpret the obtained data taking into account the interaction between chemical forms in solutions. This paper presents a general approach to studying weak ionic interactions in solutions that allows to simultaneously determine the constants of these interactions and the parameters characterizing the influence of changes in the ionic environment on these constants by the example of chlorides and bromides of alkali metals. The obtained constants for hydrosulfate-ion formation and the imperfection parameters can be a reference material for more accurate calculation of the concentration of hydrogen ions in sulfuric acid solutions. The developed approach and patterns identified in the work can be used to study the balanced states for formation of low and medium stable complexes. http://kpfu.ru/portal/docs/F1646893366/158_3_est_5.pdfsolubilityhydrosulfate ionenvironmental effects |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
M.A. Kovaleva V.A. Fedorov V.A. Ganja |
spellingShingle |
M.A. Kovaleva V.A. Fedorov V.A. Ganja Formation of Hydrogen-Ion in Isomolar Solution of Hydrochloric and Hydrobromic Acids and Their Salts Učënye Zapiski Kazanskogo Universiteta. Seriâ Estestvennye Nauki solubility hydrosulfate ion environmental effects |
author_facet |
M.A. Kovaleva V.A. Fedorov V.A. Ganja |
author_sort |
M.A. Kovaleva |
title |
Formation of Hydrogen-Ion in Isomolar Solution of Hydrochloric and Hydrobromic Acids and Their Salts |
title_short |
Formation of Hydrogen-Ion in Isomolar Solution of Hydrochloric and Hydrobromic Acids and Their Salts |
title_full |
Formation of Hydrogen-Ion in Isomolar Solution of Hydrochloric and Hydrobromic Acids and Their Salts |
title_fullStr |
Formation of Hydrogen-Ion in Isomolar Solution of Hydrochloric and Hydrobromic Acids and Their Salts |
title_full_unstemmed |
Formation of Hydrogen-Ion in Isomolar Solution of Hydrochloric and Hydrobromic Acids and Their Salts |
title_sort |
formation of hydrogen-ion in isomolar solution of hydrochloric and hydrobromic acids and their salts |
publisher |
Kazan Federal University |
series |
Učënye Zapiski Kazanskogo Universiteta. Seriâ Estestvennye Nauki |
issn |
1815-6169 2500-218X |
publishDate |
2016-09-01 |
description |
Despite the presence of a large amount of factual material on thermodynamic parameters of complexation of agents in different solvents, including mixed ones, obtained knowledge is specific in nature. In order to identify more general patterns, studies are relevant that would allow to interpret the obtained data taking into account the interaction between chemical forms in solutions.
This paper presents a general approach to studying weak ionic interactions in solutions that allows to simultaneously determine the constants of these interactions and the parameters characterizing the influence of changes in the ionic environment on these constants by the example of chlorides and bromides of alkali metals.
The obtained constants for hydrosulfate-ion formation and the imperfection parameters can be a reference material for more accurate calculation of the concentration of hydrogen ions in sulfuric acid solutions. The developed approach and patterns identified in the work can be used to study the balanced states for formation of low and medium stable complexes.
|
topic |
solubility hydrosulfate ion environmental effects |
url |
http://kpfu.ru/portal/docs/F1646893366/158_3_est_5.pdf |
work_keys_str_mv |
AT makovaleva formationofhydrogenioninisomolarsolutionofhydrochloricandhydrobromicacidsandtheirsalts AT vafedorov formationofhydrogenioninisomolarsolutionofhydrochloricandhydrobromicacidsandtheirsalts AT vaganja formationofhydrogenioninisomolarsolutionofhydrochloricandhydrobromicacidsandtheirsalts |
_version_ |
1725450094067580928 |