Chlorido{2-[(dimethylamino)methyl]phenyl-κ2C1,N}(1-methyl-1H-imidazole-κN3)palladium(II)

Chlorido{2-[(dimethylamino)methyl]phenyl-κ2C1,N}(1-methyl-1H-imidazole-κN3)palladium(II)

In the title compound, [Pd(C9H12N)Cl(C4H6N2)], which was synthesized from the reaction of 1-methylimidazole with dimeric dichloridobis[2-(dimethylamino)benzyl]palladium(II), the ring-deprotonated N,N-dimethylbenzylamine ligand acts in a C,N-bidentate fashion. The dihedral angle between the ring of t...

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Main Authors: Jason W. Clements, Milorad Stojanovic, Norris W. Hoffman, Richard E. Sykora
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810047367
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spelling doaj-2b420679adcf4264a0f4b596fa2d6a282020-11-25T01:35:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1639m164010.1107/S1600536810047367Chlorido{2-[(dimethylamino)methyl]phenyl-κ2C1,N}(1-methyl-1H-imidazole-κN3)palladium(II)Jason W. ClementsMilorad StojanovicNorris W. HoffmanRichard E. SykoraIn the title compound, [Pd(C9H12N)Cl(C4H6N2)], which was synthesized from the reaction of 1-methylimidazole with dimeric dichloridobis[2-(dimethylamino)benzyl]palladium(II), the ring-deprotonated N,N-dimethylbenzylamine ligand acts in a C,N-bidentate fashion. The dihedral angle between the ring of the 1-methylimidazole ligand and the palladacycle plane is 57.88 (16)°. The two N atoms from the N,N-dimethylbenzylamine and 1-methylimidazole ligands are trans coordinated to the PdII atom. http://scripts.iucr.org/cgi-bin/paper?S1600536810047367
collection DOAJ
language English
format Article
sources DOAJ
author Jason W. Clements
Milorad Stojanovic
Norris W. Hoffman
Richard E. Sykora
spellingShingle Jason W. Clements
Milorad Stojanovic
Norris W. Hoffman
Richard E. Sykora
Chlorido{2-[(dimethylamino)methyl]phenyl-κ2C1,N}(1-methyl-1H-imidazole-κN3)palladium(II)
Acta Crystallographica Section E
author_facet Jason W. Clements
Milorad Stojanovic
Norris W. Hoffman
Richard E. Sykora
author_sort Jason W. Clements
title Chlorido{2-[(dimethylamino)methyl]phenyl-κ2C1,N}(1-methyl-1H-imidazole-κN3)palladium(II)
title_short Chlorido{2-[(dimethylamino)methyl]phenyl-κ2C1,N}(1-methyl-1H-imidazole-κN3)palladium(II)
title_full Chlorido{2-[(dimethylamino)methyl]phenyl-κ2C1,N}(1-methyl-1H-imidazole-κN3)palladium(II)
title_fullStr Chlorido{2-[(dimethylamino)methyl]phenyl-κ2C1,N}(1-methyl-1H-imidazole-κN3)palladium(II)
title_full_unstemmed Chlorido{2-[(dimethylamino)methyl]phenyl-κ2C1,N}(1-methyl-1H-imidazole-κN3)palladium(II)
title_sort chlorido{2-[(dimethylamino)methyl]phenyl-κ2c1,n}(1-methyl-1h-imidazole-κn3)palladium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description In the title compound, [Pd(C9H12N)Cl(C4H6N2)], which was synthesized from the reaction of 1-methylimidazole with dimeric dichloridobis[2-(dimethylamino)benzyl]palladium(II), the ring-deprotonated N,N-dimethylbenzylamine ligand acts in a C,N-bidentate fashion. The dihedral angle between the ring of the 1-methylimidazole ligand and the palladacycle plane is 57.88 (16)°. The two N atoms from the N,N-dimethylbenzylamine and 1-methylimidazole ligands are trans coordinated to the PdII atom.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810047367
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AT miloradstojanovic chlorido2dimethylaminomethylphenylamp9542c1n1methyl1himidazoleamp954n3palladiumii
AT norriswhoffman chlorido2dimethylaminomethylphenylamp9542c1n1methyl1himidazoleamp954n3palladiumii
AT richardesykora chlorido2dimethylaminomethylphenylamp9542c1n1methyl1himidazoleamp954n3palladiumii
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