Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)

Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)

In the title compound, [Zn(CH3COO)2(C28H21N3O)], the ZnII ion is in a trigonal–bipyramidal ZnN3O2 coordination with a tridentate N-chelating 4′-[4-(benzyloxy)phenyl)-2,2′:6′,2′′-terpyridine ligand in the equatorial p...

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Main Authors: Zhan Guo Lu, Wei Li
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809049502
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spelling doaj-2c5fc998a4cc49f1ba21d4aa4ecf8ccb2020-11-25T01:56:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1672m167210.1107/S1600536809049502Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)Zhan Guo LuWei LiIn the title compound, [Zn(CH3COO)2(C28H21N3O)], the ZnII ion is in a trigonal–bipyramidal ZnN3O2 coordination with a tridentate N-chelating 4′-[4-(benzyloxy)phenyl)-2,2′:6′,2′′-terpyridine ligand in the equatorial position and two acetate anions in the axial positions. The three pyridine rings are approximately coplanar, with a maximum deviation of 0.03 Å from the mean plane. The phenoxy substituent makes a dihedral angle of 18.1 (2)° with the central pyridine ring. The benzyl group has a C—O—C—C torsion angle of 77.62 (8)° relative to the phenoxy ring. In the crystal, molecules are linked via C—H...O hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536809049502
collection DOAJ
language English
format Article
sources DOAJ
author Zhan Guo Lu
Wei Li
spellingShingle Zhan Guo Lu
Wei Li
Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)
Acta Crystallographica Section E
author_facet Zhan Guo Lu
Wei Li
author_sort Zhan Guo Lu
title Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)
title_short Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)
title_full Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)
title_fullStr Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)
title_full_unstemmed Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)
title_sort diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description In the title compound, [Zn(CH3COO)2(C28H21N3O)], the ZnII ion is in a trigonal–bipyramidal ZnN3O2 coordination with a tridentate N-chelating 4′-[4-(benzyloxy)phenyl)-2,2′:6′,2′′-terpyridine ligand in the equatorial position and two acetate anions in the axial positions. The three pyridine rings are approximately coplanar, with a maximum deviation of 0.03 Å from the mean plane. The phenoxy substituent makes a dihedral angle of 18.1 (2)° with the central pyridine ring. The benzyl group has a C—O—C—C torsion angle of 77.62 (8)° relative to the phenoxy ring. In the crystal, molecules are linked via C—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809049502
work_keys_str_mv AT zhanguolu diacetato4amp82424benzyloxyphenyl22amp82426amp82422amp8242amp8242terpyridinezincii
AT weili diacetato4amp82424benzyloxyphenyl22amp82426amp82422amp8242amp8242terpyridinezincii
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