A new Schiff base nickel(II) complex: {5,5′-dihydroxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) methanol disolvate
The monomeric title nickel(II) complex of a salicylaldimine, [Ni(C20H14N2O4)]·2CH3OH, was obtained by the reaction of 2,4-dihydroxybenzaldehyde and 1,2-phenylenediamine with nickel(II) acetate. The NiII atom is coordinated by two N atoms [Ni—N = 1.839 (2)&...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680904063X |
| Summary: | The monomeric title nickel(II) complex of a salicylaldimine, [Ni(C20H14N2O4)]·2CH3OH, was obtained by the reaction of 2,4-dihydroxybenzaldehyde and 1,2-phenylenediamine with nickel(II) acetate. The NiII atom is coordinated by two N atoms [Ni—N = 1.839 (2) Å] and two O atoms [Ni—O = 1.8253 (19) Å] in an approximately square-planar geometry. In the crystal structure, intermolecular O—H...O hydrogen bonds link the molecules into a chain along [001]. |
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| ISSN: | 1600-5368 |