Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid

Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid

C–H bond functionalization has become an important tool for many organic transformations, however such reactions typically require stoichiometric amounts of external oxidants. Here the authors report the photo-driven decarboxylative C–H trifluoromethylation of arenes using only low amounts of oxidan...

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Main Authors: Jin Lin, Zhi Li, Jian Kan, Shijun Huang, Weiping Su, Yadong Li
Format: Article
Language:English
Published: Nature Publishing Group 2017-02-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/ncomms14353
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spelling doaj-2e18733cf7704f7abc21025d655479752021-05-11T07:28:39ZengNature Publishing GroupNature Communications2041-17232017-02-01811710.1038/ncomms14353Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acidJin Lin0Zhi Li1Jian Kan2Shijun Huang3Weiping Su4Yadong Li5State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesDepartment of Chemistry, Tsinghua UniversityState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesDepartment of Chemistry, Tsinghua UniversityC–H bond functionalization has become an important tool for many organic transformations, however such reactions typically require stoichiometric amounts of external oxidants. Here the authors report the photo-driven decarboxylative C–H trifluoromethylation of arenes using only low amounts of oxidant.https://doi.org/10.1038/ncomms14353
collection DOAJ
language English
format Article
sources DOAJ
author Jin Lin
Zhi Li
Jian Kan
Shijun Huang
Weiping Su
Yadong Li
spellingShingle Jin Lin
Zhi Li
Jian Kan
Shijun Huang
Weiping Su
Yadong Li
Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
Nature Communications
author_facet Jin Lin
Zhi Li
Jian Kan
Shijun Huang
Weiping Su
Yadong Li
author_sort Jin Lin
title Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
title_short Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
title_full Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
title_fullStr Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
title_full_unstemmed Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
title_sort photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2017-02-01
description C–H bond functionalization has become an important tool for many organic transformations, however such reactions typically require stoichiometric amounts of external oxidants. Here the authors report the photo-driven decarboxylative C–H trifluoromethylation of arenes using only low amounts of oxidant.
url https://doi.org/10.1038/ncomms14353
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AT zhili photodrivenredoxneutraldecarboxylativecarbonhydrogentrifluoromethylationofheteroareneswithtrifluoroaceticacid
AT jiankan photodrivenredoxneutraldecarboxylativecarbonhydrogentrifluoromethylationofheteroareneswithtrifluoroaceticacid
AT shijunhuang photodrivenredoxneutraldecarboxylativecarbonhydrogentrifluoromethylationofheteroareneswithtrifluoroaceticacid
AT weipingsu photodrivenredoxneutraldecarboxylativecarbonhydrogentrifluoromethylationofheteroareneswithtrifluoroaceticacid
AT yadongli photodrivenredoxneutraldecarboxylativecarbonhydrogentrifluoromethylationofheteroareneswithtrifluoroaceticacid
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