Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]

Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]

The title compound, [Mn2(HO3PCH2CH2COO)2(C8H8N2)2(H2O)2], was obtained by hydrothermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The d...

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Main Authors: Shao-Ming Ying, Yun Chen, Qiu-Yan Luo, Ya-Ping Xv, Dong-Sheng Liu
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807065142
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spelling doaj-2e384324b6c74656b1a176241cecf8ee2020-11-25T00:12:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m166m16610.1107/S1600536807065142Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]Shao-Ming YingYun ChenQiu-Yan LuoYa-Ping XvDong-Sheng LiuThe title compound, [Mn2(HO3PCH2CH2COO)2(C8H8N2)2(H2O)2], was obtained by hydrothermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The dimers are further linked by O—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distance 4.2754 (4) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536807065142
collection DOAJ
language English
format Article
sources DOAJ
author Shao-Ming Ying
Yun Chen
Qiu-Yan Luo
Ya-Ping Xv
Dong-Sheng Liu
spellingShingle Shao-Ming Ying
Yun Chen
Qiu-Yan Luo
Ya-Ping Xv
Dong-Sheng Liu
Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]
Acta Crystallographica Section E
author_facet Shao-Ming Ying
Yun Chen
Qiu-Yan Luo
Ya-Ping Xv
Dong-Sheng Liu
author_sort Shao-Ming Ying
title Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]
title_short Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]
title_full Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]
title_fullStr Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]
title_full_unstemmed Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]
title_sort bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description The title compound, [Mn2(HO3PCH2CH2COO)2(C8H8N2)2(H2O)2], was obtained by hydrothermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The dimers are further linked by O—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distance 4.2754 (4) Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536807065142
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AT yunchen bis956carboxylatoethylphosphonatobisaqua228242bipyridinemanganeseii
AT qiuyanluo bis956carboxylatoethylphosphonatobisaqua228242bipyridinemanganeseii
AT yapingxv bis956carboxylatoethylphosphonatobisaqua228242bipyridinemanganeseii
AT dongshengliu bis956carboxylatoethylphosphonatobisaqua228242bipyridinemanganeseii
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