Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]
The title compound, [Mn2(HO3PCH2CH2COO)2(C8H8N2)2(H2O)2], was obtained by hydrothermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The d...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2008-01-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807065142 |
id |
doaj-2e384324b6c74656b1a176241cecf8ee |
---|---|
record_format |
Article |
spelling |
doaj-2e384324b6c74656b1a176241cecf8ee2020-11-25T00:12:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m166m16610.1107/S1600536807065142Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]Shao-Ming YingYun ChenQiu-Yan LuoYa-Ping XvDong-Sheng LiuThe title compound, [Mn2(HO3PCH2CH2COO)2(C8H8N2)2(H2O)2], was obtained by hydrothermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The dimers are further linked by O—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distance 4.2754 (4) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536807065142 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Shao-Ming Ying Yun Chen Qiu-Yan Luo Ya-Ping Xv Dong-Sheng Liu |
spellingShingle |
Shao-Ming Ying Yun Chen Qiu-Yan Luo Ya-Ping Xv Dong-Sheng Liu Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] Acta Crystallographica Section E |
author_facet |
Shao-Ming Ying Yun Chen Qiu-Yan Luo Ya-Ping Xv Dong-Sheng Liu |
author_sort |
Shao-Ming Ying |
title |
Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] |
title_short |
Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] |
title_full |
Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] |
title_fullStr |
Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] |
title_full_unstemmed |
Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] |
title_sort |
bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(ii)] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2008-01-01 |
description |
The title compound, [Mn2(HO3PCH2CH2COO)2(C8H8N2)2(H2O)2], was obtained by hydrothermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The dimers are further linked by O—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distance 4.2754 (4) Å]. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536807065142 |
work_keys_str_mv |
AT shaomingying bis956carboxylatoethylphosphonatobisaqua228242bipyridinemanganeseii AT yunchen bis956carboxylatoethylphosphonatobisaqua228242bipyridinemanganeseii AT qiuyanluo bis956carboxylatoethylphosphonatobisaqua228242bipyridinemanganeseii AT yapingxv bis956carboxylatoethylphosphonatobisaqua228242bipyridinemanganeseii AT dongshengliu bis956carboxylatoethylphosphonatobisaqua228242bipyridinemanganeseii |
_version_ |
1725397826273280000 |