3-Chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-one
Stille coupling of 5-chloro-4-oxo-4H-1,2,6-thiadiazin-3-yl trifluoromethanesulfonate (7) with tributyl(3-n-hexylthien-2-yl)stannane and Pd(Ph3P)2Cl2 in PhMe at ca. 20 °C, for 24 h gave 3-chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-one (9) with a 60% yield. The latter is a potentially useful...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2019-01-01
|
| Series: | Molbank |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1422-8599/2019/1/M1043 |
| id |
doaj-2f290a105da4430db7e95f70189ce593 |
|---|---|
| record_format |
Article |
| spelling |
doaj-2f290a105da4430db7e95f70189ce5932020-11-24T20:42:06ZengMDPI AGMolbank1422-85992019-01-0120191M104310.3390/M1043M10433-Chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-oneAndreas S. Kalogirou0Panayiotis A. Koutentis1Department of Life Sciences, School of Sciences, European University Cyprus, 6 Diogenis Str., Engomi, P. O. Box 22006, 1516 Nicosia, CyprusDepartment of Chemistry, University of Cyprus; P.O. Box 20537, 1678 Nicosia, CyprusStille coupling of 5-chloro-4-oxo-4H-1,2,6-thiadiazin-3-yl trifluoromethanesulfonate (7) with tributyl(3-n-hexylthien-2-yl)stannane and Pd(Ph3P)2Cl2 in PhMe at ca. 20 °C, for 24 h gave 3-chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-one (9) with a 60% yield. The latter is a potentially useful building block for the synthesis of oligomeric and polymeric donors for organic photovoltaics.http://www.mdpi.com/1422-8599/2019/1/M1043Stilleheterocycle1,2,6-thiadiazinehexylthiopheneunsymmetrical |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Andreas S. Kalogirou Panayiotis A. Koutentis |
| spellingShingle |
Andreas S. Kalogirou Panayiotis A. Koutentis 3-Chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-one Molbank Stille heterocycle 1,2,6-thiadiazine hexylthiophene unsymmetrical |
| author_facet |
Andreas S. Kalogirou Panayiotis A. Koutentis |
| author_sort |
Andreas S. Kalogirou |
| title |
3-Chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-one |
| title_short |
3-Chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-one |
| title_full |
3-Chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-one |
| title_fullStr |
3-Chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-one |
| title_full_unstemmed |
3-Chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-one |
| title_sort |
3-chloro-5-(3-n-hexylthien-2-yl)-4h-1,2,6-thiadiazin-4-one |
| publisher |
MDPI AG |
| series |
Molbank |
| issn |
1422-8599 |
| publishDate |
2019-01-01 |
| description |
Stille coupling of 5-chloro-4-oxo-4H-1,2,6-thiadiazin-3-yl trifluoromethanesulfonate (7) with tributyl(3-n-hexylthien-2-yl)stannane and Pd(Ph3P)2Cl2 in PhMe at ca. 20 °C, for 24 h gave 3-chloro-5-(3-n-hexylthien-2-yl)-4H-1,2,6-thiadiazin-4-one (9) with a 60% yield. The latter is a potentially useful building block for the synthesis of oligomeric and polymeric donors for organic photovoltaics. |
| topic |
Stille heterocycle 1,2,6-thiadiazine hexylthiophene unsymmetrical |
| url |
http://www.mdpi.com/1422-8599/2019/1/M1043 |
| work_keys_str_mv |
AT andreasskalogirou 3chloro53nhexylthien2yl4h126thiadiazin4one AT panayiotisakoutentis 3chloro53nhexylthien2yl4h126thiadiazin4one |
| _version_ |
1716823214178435072 |