Crystal Structure of [Bis(DIMETHYLFORMAMIDE) Bis (2,2’-PYRIDYL)QUINOLINE) Iron (II)] Bis-(TETRAPHENYLBORATE)
The goal of this research is to obtain single crystal and structural information of iron(II) complex with 2,(2'-pyridyl)quinoline(pq) ligands. The reaction of iron(II) salt with 2,(2'-pyridyl)quinoline ligand and sodiumtetraphenylborate in the molar ratio of 1:3:2 in methanol-N,N-dimethylf...
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Universitas Indonesia
2009-11-01
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doaj-2fcfae11bc014547aa8cfd02fdd00bb92020-11-24T23:23:59ZengUniversitas IndonesiaMakara Seri Sains1693-66712009-11-01132101104Crystal Structure of [Bis(DIMETHYLFORMAMIDE) Bis (2,2’-PYRIDYL)QUINOLINE) Iron (II)] Bis-(TETRAPHENYLBORATE)Bohari M. YaminSusanto Imam RahayuIsmunandarDjulia OnggoIis Siti JahroThe goal of this research is to obtain single crystal and structural information of iron(II) complex with 2,(2'-pyridyl)quinoline(pq) ligands. The reaction of iron(II) salt with 2,(2'-pyridyl)quinoline ligand and sodiumtetraphenylborate in the molar ratio of 1:3:2 in methanol-N,N-dimethylformamide(dmf) solution results in an iron(II)complex. The formula of the [Fe(pq)2(dmf)2](BPh4)2 complex has been obtained from the iron(II) and C, H, N contents.Single crystal of [Fe(pq)2(dmf)2](BPh4)2 suitable for X-ray investigation was obtained by evaporation of the complexsolution in N,N-dimethylformamide at room temperature after 24 hours. This compound crystallizes in monoclinicsystem with C2/c space group, a = 27.950(4), b = 14.169(7), c = 17.717(9) Å and b = 105.669(11)°. The structureconsist of iron(II) is chelated by two pq ligands through the N atoms and two dmf molecules in a six-coordinationenvironment. The charge of the [Fe(pq)2(dmf)2]2+ cation is balanced by two tetraphenylborate (BPh4)- anions.http://journal.ui.ac.id/science/article/view/399crystal structuredistorted octahedral[Fe(pq)2(dmf)2](BPh4)2 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Bohari M. Yamin Susanto Imam Rahayu Ismunandar Djulia Onggo Iis Siti Jahro |
spellingShingle |
Bohari M. Yamin Susanto Imam Rahayu Ismunandar Djulia Onggo Iis Siti Jahro Crystal Structure of [Bis(DIMETHYLFORMAMIDE) Bis (2,2’-PYRIDYL)QUINOLINE) Iron (II)] Bis-(TETRAPHENYLBORATE) Makara Seri Sains crystal structure distorted octahedral [Fe(pq)2(dmf)2](BPh4)2 |
author_facet |
Bohari M. Yamin Susanto Imam Rahayu Ismunandar Djulia Onggo Iis Siti Jahro |
author_sort |
Bohari M. Yamin |
title |
Crystal Structure of [Bis(DIMETHYLFORMAMIDE) Bis (2,2’-PYRIDYL)QUINOLINE) Iron (II)] Bis-(TETRAPHENYLBORATE) |
title_short |
Crystal Structure of [Bis(DIMETHYLFORMAMIDE) Bis (2,2’-PYRIDYL)QUINOLINE) Iron (II)] Bis-(TETRAPHENYLBORATE) |
title_full |
Crystal Structure of [Bis(DIMETHYLFORMAMIDE) Bis (2,2’-PYRIDYL)QUINOLINE) Iron (II)] Bis-(TETRAPHENYLBORATE) |
title_fullStr |
Crystal Structure of [Bis(DIMETHYLFORMAMIDE) Bis (2,2’-PYRIDYL)QUINOLINE) Iron (II)] Bis-(TETRAPHENYLBORATE) |
title_full_unstemmed |
Crystal Structure of [Bis(DIMETHYLFORMAMIDE) Bis (2,2’-PYRIDYL)QUINOLINE) Iron (II)] Bis-(TETRAPHENYLBORATE) |
title_sort |
crystal structure of [bis(dimethylformamide) bis (2,2’-pyridyl)quinoline) iron (ii)] bis-(tetraphenylborate) |
publisher |
Universitas Indonesia |
series |
Makara Seri Sains |
issn |
1693-6671 |
publishDate |
2009-11-01 |
description |
The goal of this research is to obtain single crystal and structural information of iron(II) complex with 2,(2'-pyridyl)quinoline(pq) ligands. The reaction of iron(II) salt with 2,(2'-pyridyl)quinoline ligand and sodiumtetraphenylborate in the molar ratio of 1:3:2 in methanol-N,N-dimethylformamide(dmf) solution results in an iron(II)complex. The formula of the [Fe(pq)2(dmf)2](BPh4)2 complex has been obtained from the iron(II) and C, H, N contents.Single crystal of [Fe(pq)2(dmf)2](BPh4)2 suitable for X-ray investigation was obtained by evaporation of the complexsolution in N,N-dimethylformamide at room temperature after 24 hours. This compound crystallizes in monoclinicsystem with C2/c space group, a = 27.950(4), b = 14.169(7), c = 17.717(9) Å and b = 105.669(11)°. The structureconsist of iron(II) is chelated by two pq ligands through the N atoms and two dmf molecules in a six-coordinationenvironment. The charge of the [Fe(pq)2(dmf)2]2+ cation is balanced by two tetraphenylborate (BPh4)- anions. |
topic |
crystal structure distorted octahedral [Fe(pq)2(dmf)2](BPh4)2 |
url |
http://journal.ui.ac.id/science/article/view/399 |
work_keys_str_mv |
AT boharimyamin crystalstructureofbisdimethylformamidebis22pyridylquinolineironiibistetraphenylborate AT susantoimamrahayu crystalstructureofbisdimethylformamidebis22pyridylquinolineironiibistetraphenylborate AT ismunandar crystalstructureofbisdimethylformamidebis22pyridylquinolineironiibistetraphenylborate AT djuliaonggo crystalstructureofbisdimethylformamidebis22pyridylquinolineironiibistetraphenylborate AT iissitijahro crystalstructureofbisdimethylformamidebis22pyridylquinolineironiibistetraphenylborate |
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1725562582985605120 |