Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate

Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate

In the title compound, [Co(C5H4NO3)2(H2O)2]·2H2O, the coordination polyhedron around the six-coordinate CoII ion is formed by two equatorial 5-methylisoxazole-3-carboxylate ligands in an N,O3-bidentate fashion through the isoxazole N atom and a carboxylate O atom, and by two axial water...

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Main Authors: Yan Wang, Jing Zhao
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811053414
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spelling doaj-30417b8c5fa04017ae7e02aa509c30d92020-11-25T01:22:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m69m6910.1107/S1600536811053414Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrateYan WangJing ZhaoIn the title compound, [Co(C5H4NO3)2(H2O)2]·2H2O, the coordination polyhedron around the six-coordinate CoII ion is formed by two equatorial 5-methylisoxazole-3-carboxylate ligands in an N,O3-bidentate fashion through the isoxazole N atom and a carboxylate O atom, and by two axial water ligands. The asymmetric unit consists of half of the complex and one water molecule (the full comlex being completed by application of inversion). In the crystal, the water molecules participate in the formation of an intricate three-dimensional network of hydrogen bonds involving the coordinated water molecule and the carboxylate groups.http://scripts.iucr.org/cgi-bin/paper?S1600536811053414
collection DOAJ
language English
format Article
sources DOAJ
author Yan Wang
Jing Zhao
spellingShingle Yan Wang
Jing Zhao
Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate
Acta Crystallographica Section E
author_facet Yan Wang
Jing Zhao
author_sort Yan Wang
title Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate
title_short Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate
title_full Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate
title_fullStr Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate
title_full_unstemmed Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2N,O3)cobalt(II) dihydrate
title_sort diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ2n,o3)cobalt(ii) dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-01-01
description In the title compound, [Co(C5H4NO3)2(H2O)2]·2H2O, the coordination polyhedron around the six-coordinate CoII ion is formed by two equatorial 5-methylisoxazole-3-carboxylate ligands in an N,O3-bidentate fashion through the isoxazole N atom and a carboxylate O atom, and by two axial water ligands. The asymmetric unit consists of half of the complex and one water molecule (the full comlex being completed by application of inversion). In the crystal, the water molecules participate in the formation of an intricate three-dimensional network of hydrogen bonds involving the coordinated water molecule and the carboxylate groups.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811053414
work_keys_str_mv AT yanwang diaquabis5methyl12oxazole3carboxylatoamp9542no3cobaltiidihydrate
AT jingzhao diaquabis5methyl12oxazole3carboxylatoamp9542no3cobaltiidihydrate
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