catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)]

catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)]

The title complex, [Pb(C8H5N2O2S)2]n, consists of one PbII ion located on a crystallographic twofold axis and two symmetry-related 2-amino-1,3-benzothiazole-6-carboxylate (ABTC) ligands. The central PbII ion has a (4 + 2) coordination by four O atoms of the two ABTC ligands...

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Main Authors: Jun-Dong Wang, Xin Fang, Hua Ke, Hai-Yang Yu, Ke-Ke Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810049330
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spelling doaj-30d07103e2f84ddc92b2822f43fc61d32020-11-24T21:26:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1700m170110.1107/S1600536810049330catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)]Jun-Dong WangXin FangHua KeHai-Yang YuKe-Ke ZhangThe title complex, [Pb(C8H5N2O2S)2]n, consists of one PbII ion located on a crystallographic twofold axis and two symmetry-related 2-amino-1,3-benzothiazole-6-carboxylate (ABTC) ligands. The central PbII ion has a (4 + 2) coordination by four O atoms of the two ABTC ligands and two weaker Pb—S bonding interactions (Pb—S secondary bonds) from S atoms of other two neighbouring ABTC ligands. These bonds link the metal ions into zigzag chains along the c axis, which, in turn, aggregate through π–π interactions [centroid–centroid distance = 3.7436 Å] between ABTC rings and N—H...O and N—H...N hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536810049330
collection DOAJ
language English
format Article
sources DOAJ
author Jun-Dong Wang
Xin Fang
Hua Ke
Hai-Yang Yu
Ke-Ke Zhang
spellingShingle Jun-Dong Wang
Xin Fang
Hua Ke
Hai-Yang Yu
Ke-Ke Zhang
catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)]
Acta Crystallographica Section E
author_facet Jun-Dong Wang
Xin Fang
Hua Ke
Hai-Yang Yu
Ke-Ke Zhang
author_sort Jun-Dong Wang
title catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)]
title_short catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)]
title_full catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)]
title_fullStr catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)]
title_full_unstemmed catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)]
title_sort catena-poly[lead(ii)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description The title complex, [Pb(C8H5N2O2S)2]n, consists of one PbII ion located on a crystallographic twofold axis and two symmetry-related 2-amino-1,3-benzothiazole-6-carboxylate (ABTC) ligands. The central PbII ion has a (4 + 2) coordination by four O atoms of the two ABTC ligands and two weaker Pb—S bonding interactions (Pb—S secondary bonds) from S atoms of other two neighbouring ABTC ligands. These bonds link the metal ions into zigzag chains along the c axis, which, in turn, aggregate through π–π interactions [centroid–centroid distance = 3.7436 Å] between ABTC rings and N—H...O and N—H...N hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810049330
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AT xinfang catenapolyleadiibisamp9562amino13benzothiazole6carboxylato
AT huake catenapolyleadiibisamp9562amino13benzothiazole6carboxylato
AT haiyangyu catenapolyleadiibisamp9562amino13benzothiazole6carboxylato
AT kekezhang catenapolyleadiibisamp9562amino13benzothiazole6carboxylato
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