Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)cobalt(II) butane-2,3-diol monosolvate
In the title compound, [Co(SO4)(C12H8N2)2]·C4H10O2, the Co2+ ion has a distorted octahedral coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate anion. The dihedral angle between the...
Main Authors: | , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2011-04-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811009147 |
id |
doaj-31819edc4f204fd38b509edf4ee3c59a |
---|---|
record_format |
Article |
spelling |
doaj-31819edc4f204fd38b509edf4ee3c59a2020-11-25T01:38:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674m446m44610.1107/S1600536811009147Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)cobalt(II) butane-2,3-diol monosolvateShi-Juan WangKai-Long ZhongIn the title compound, [Co(SO4)(C12H8N2)2]·C4H10O2, the Co2+ ion has a distorted octahedral coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate anion. The dihedral angle between the two chelating N2C2 groups is 83.48 (1)°. The Co2+ ion, the S atom and the mid-point of the central C—C bond of the butane-2,3-diol solvent molecule are situated on twofold rotation axes. The molecules of the complex and the solvent molecules are held together by pairs of symmetry-related O—H...O hydrogen bonds with the uncoordinated O atoms of the sulfate ions as acceptors. The solvent molecule is disordered over two sets of sites with site occupancies of 0.40 and 0.60. http://scripts.iucr.org/cgi-bin/paper?S1600536811009147 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Shi-Juan Wang Kai-Long Zhong |
spellingShingle |
Shi-Juan Wang Kai-Long Zhong Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)cobalt(II) butane-2,3-diol monosolvate Acta Crystallographica Section E |
author_facet |
Shi-Juan Wang Kai-Long Zhong |
author_sort |
Shi-Juan Wang |
title |
Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)cobalt(II) butane-2,3-diol monosolvate |
title_short |
Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)cobalt(II) butane-2,3-diol monosolvate |
title_full |
Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)cobalt(II) butane-2,3-diol monosolvate |
title_fullStr |
Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)cobalt(II) butane-2,3-diol monosolvate |
title_full_unstemmed |
Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)cobalt(II) butane-2,3-diol monosolvate |
title_sort |
bis(1,10-phenanthroline-κ2n,n′)(sulfato-κ2o,o′)cobalt(ii) butane-2,3-diol monosolvate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2011-04-01 |
description |
In the title compound, [Co(SO4)(C12H8N2)2]·C4H10O2, the Co2+ ion has a distorted octahedral coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate anion. The dihedral angle between the two chelating N2C2 groups is 83.48 (1)°. The Co2+ ion, the S atom and the mid-point of the central C—C bond of the butane-2,3-diol solvent molecule are situated on twofold rotation axes. The molecules of the complex and the solvent molecules are held together by pairs of symmetry-related O—H...O hydrogen bonds with the uncoordinated O atoms of the sulfate ions as acceptors. The solvent molecule is disordered over two sets of sites with site occupancies of 0.40 and 0.60. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811009147 |
work_keys_str_mv |
AT shijuanwang bis110phenanthrolineamp9542nnamp8242sulfatoamp9542ooamp8242cobaltiibutane23diolmonosolvate AT kailongzhong bis110phenanthrolineamp9542nnamp8242sulfatoamp9542ooamp8242cobaltiibutane23diolmonosolvate |
_version_ |
1725055782175637504 |