{2-[(Benzylphenylphosphanyl-κP)methyl]phenyl-κC1}iodidobis(trimethylphosphane)cobalt(II)

{2-[(Benzylphenylphosphanyl-κP)methyl]phenyl-κC1}iodidobis(trimethylphosphane)cobalt(II)

In the title compound, [Co(C20H18P)I(C3H9P)2], the CoII atom has a distorted square-pyramidal geometry, the base of which is comprised of two trans PMe3 groups, an I atom, and a C atom of the benzyl group. This benzyl group is tethered to the P atom at the apex of the pyramid, thereby forming a five...

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Main Authors: Jiong Jia, Chenggen Wang, Nazhen Liu, Xiaoyan Li
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811022288
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spelling doaj-32d91738e2ed4513a8f70f3d1c057f032020-11-25T02:30:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m991m99110.1107/S1600536811022288{2-[(Benzylphenylphosphanyl-κP)methyl]phenyl-κC1}iodidobis(trimethylphosphane)cobalt(II)Jiong JiaChenggen WangNazhen LiuXiaoyan LiIn the title compound, [Co(C20H18P)I(C3H9P)2], the CoII atom has a distorted square-pyramidal geometry, the base of which is comprised of two trans PMe3 groups, an I atom, and a C atom of the benzyl group. This benzyl group is tethered to the P atom at the apex of the pyramid, thereby forming a five-membered chelated Co—C—C—C—P ring.http://scripts.iucr.org/cgi-bin/paper?S1600536811022288
collection DOAJ
language English
format Article
sources DOAJ
author Jiong Jia
Chenggen Wang
Nazhen Liu
Xiaoyan Li
spellingShingle Jiong Jia
Chenggen Wang
Nazhen Liu
Xiaoyan Li
{2-[(Benzylphenylphosphanyl-κP)methyl]phenyl-κC1}iodidobis(trimethylphosphane)cobalt(II)
Acta Crystallographica Section E
author_facet Jiong Jia
Chenggen Wang
Nazhen Liu
Xiaoyan Li
author_sort Jiong Jia
title {2-[(Benzylphenylphosphanyl-κP)methyl]phenyl-κC1}iodidobis(trimethylphosphane)cobalt(II)
title_short {2-[(Benzylphenylphosphanyl-κP)methyl]phenyl-κC1}iodidobis(trimethylphosphane)cobalt(II)
title_full {2-[(Benzylphenylphosphanyl-κP)methyl]phenyl-κC1}iodidobis(trimethylphosphane)cobalt(II)
title_fullStr {2-[(Benzylphenylphosphanyl-κP)methyl]phenyl-κC1}iodidobis(trimethylphosphane)cobalt(II)
title_full_unstemmed {2-[(Benzylphenylphosphanyl-κP)methyl]phenyl-κC1}iodidobis(trimethylphosphane)cobalt(II)
title_sort {2-[(benzylphenylphosphanyl-κp)methyl]phenyl-κc1}iodidobis(trimethylphosphane)cobalt(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-07-01
description In the title compound, [Co(C20H18P)I(C3H9P)2], the CoII atom has a distorted square-pyramidal geometry, the base of which is comprised of two trans PMe3 groups, an I atom, and a C atom of the benzyl group. This benzyl group is tethered to the P atom at the apex of the pyramid, thereby forming a five-membered chelated Co—C—C—C—P ring.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811022288
work_keys_str_mv AT jiongjia 2benzylphenylphosphanylamp954pmethylphenylamp954c1iodidobistrimethylphosphanecobaltii
AT chenggenwang 2benzylphenylphosphanylamp954pmethylphenylamp954c1iodidobistrimethylphosphanecobaltii
AT nazhenliu 2benzylphenylphosphanylamp954pmethylphenylamp954c1iodidobistrimethylphosphanecobaltii
AT xiaoyanli 2benzylphenylphosphanylamp954pmethylphenylamp954c1iodidobistrimethylphosphanecobaltii
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