Kinetics Study of the Hydrodeoxygenation of Xylitol over a ReO_x-Pd/CeO₂ Catalyst

• Main Authors: Blake MacQueen, Michael Royko, Bradie S. Crandall, Andreas Heyden, Yomaira J. Pagán-Torres, Jochen Lauterbach
• Format: Article
• Language: English
• Published: MDPI AG 2021-01-01
• Series: Catalysts
• Subjects: heterogeneous catalysis; kinetics; hydrodeoxygenation; xylitol; Rhenium; biomass upgrading
• Online Access: https://www.mdpi.com/2073-4344/11/1/108

In this study, we elucidate the reaction kinetics for the simultaneous hydrodeoxygenation of xylitol to 1,2-dideoxypentitol and 1,2,5-pentanetriol over a ReO_x-Pd/CeO₂ (2.0 weight% Re, 0.30 weight% Pd) catalyst. The reaction was determined to be a zero-order reaction with respect to xylitol. The activation energy was elucidated through an Arrhenius relationship as well as non-Arrhenius kinetics. The Arrhenius relationship was investigated at 150–170 °C and a constant H₂ pressure of 10 bar resulting in an activation energy of 48.7 ± 10.5 kJ/mol. The investigation of non-Arrhenius kinetics was conducted at 120–170 °C and a sub-Arrhenius relation was elucidated with activation energy being dependent on temperature, and ranging from 10.2–51.8 kJ/mol in the temperature range investigated. Internal and external mass transfer were investigated through evaluating the Weisz–Prater criterion and the effect of varying stirring rate on the reaction rate, respectively. There were no internal or external mass transfer limitations present in the reaction.