Mechanochemical treatment of Serbian kaolin clay to obtain high reactive pozzolana
Mechanochemical treatment of Serbian kaolin clay was carried out in a planetary ball mill using two different milling media, hardened steel or zirconia vials and balls. The samples obtained with various milling times were characterized by the particle size laser diffraction (PSLD), X-ray diffrac...
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Serbian Chemical Society
2013-01-01
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doaj-33f6b021b1cc48d8aa7956752e5af2612020-11-24T22:33:30ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51392013-01-0178457959010.2298/JSC120829107MMechanochemical treatment of Serbian kaolin clay to obtain high reactive pozzolanaMitrović AleksandraZdujić MiodragMechanochemical treatment of Serbian kaolin clay was carried out in a planetary ball mill using two different milling media, hardened steel or zirconia vials and balls. The samples obtained with various milling times were characterized by the particle size laser diffraction (PSLD), X-ray diffraction (XRD), differential scanning calorimetry/thermogravimetry (DTA/TGA) and Fourier-transform infrared (FTIR) analyses. Mechanochemical treatment induced amorphization of the kaolinite phase accompanied by dehydroxylation. It was found that for the given milling parameters, amorphization mainly took place in the milling period up to 15 min, and was completed after about 30 min of milling for both milling media used. The pozzolanic activities were determined by the Chapelle method. Milling in the hardened steel milling medium had no significant influence on pozzolanic activity, even though there was accumulated iron contamination. For both milling media, pozzolanic activity of 0.79 was obtained for the samples milled for 15 min and it remained almost unchanged with prolonged milling. The determined pozzolanic activity values are close to these of commercial metakaolinite or metakaolinite obtained by the calcination of the same clay, therefore, indicating possibility for obtaining high reactive pozzolana by mechanochemical treatment of Serbian kaoline clay. [Projekat Ministarstva nauke Republike Srbije, br. TR 36017 and 45001]http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391200107M.pdfkaolin claykaolinitemetakaolinitemechanochemical treatmentpozzolana |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Mitrović Aleksandra Zdujić Miodrag |
spellingShingle |
Mitrović Aleksandra Zdujić Miodrag Mechanochemical treatment of Serbian kaolin clay to obtain high reactive pozzolana Journal of the Serbian Chemical Society kaolin clay kaolinite metakaolinite mechanochemical treatment pozzolana |
author_facet |
Mitrović Aleksandra Zdujić Miodrag |
author_sort |
Mitrović Aleksandra |
title |
Mechanochemical treatment of Serbian kaolin clay to obtain high reactive pozzolana |
title_short |
Mechanochemical treatment of Serbian kaolin clay to obtain high reactive pozzolana |
title_full |
Mechanochemical treatment of Serbian kaolin clay to obtain high reactive pozzolana |
title_fullStr |
Mechanochemical treatment of Serbian kaolin clay to obtain high reactive pozzolana |
title_full_unstemmed |
Mechanochemical treatment of Serbian kaolin clay to obtain high reactive pozzolana |
title_sort |
mechanochemical treatment of serbian kaolin clay to obtain high reactive pozzolana |
publisher |
Serbian Chemical Society |
series |
Journal of the Serbian Chemical Society |
issn |
0352-5139 |
publishDate |
2013-01-01 |
description |
Mechanochemical treatment of Serbian kaolin clay was carried out in a planetary ball mill using two different milling media, hardened steel or zirconia vials and balls. The samples obtained with various milling times were characterized by the particle size laser diffraction (PSLD), X-ray diffraction (XRD), differential scanning calorimetry/thermogravimetry (DTA/TGA) and Fourier-transform infrared (FTIR) analyses. Mechanochemical treatment induced amorphization of the kaolinite phase accompanied by dehydroxylation. It was found that for the given milling parameters, amorphization mainly took place in the milling period up to 15 min, and was completed after about 30 min of milling for both milling media used. The pozzolanic activities were determined by the Chapelle method. Milling in the hardened steel milling medium had no significant influence on pozzolanic activity, even though there was accumulated iron contamination. For both milling media, pozzolanic activity of 0.79 was obtained for the samples milled for 15 min and it remained almost unchanged with prolonged milling. The determined pozzolanic activity values are close to these of commercial metakaolinite or metakaolinite obtained by the calcination of the same clay, therefore, indicating possibility for obtaining high reactive pozzolana by mechanochemical treatment of Serbian kaoline clay. [Projekat Ministarstva nauke Republike Srbije, br. TR 36017 and 45001] |
topic |
kaolin clay kaolinite metakaolinite mechanochemical treatment pozzolana |
url |
http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391200107M.pdf |
work_keys_str_mv |
AT mitrovicaleksandra mechanochemicaltreatmentofserbiankaolinclaytoobtainhighreactivepozzolana AT zdujicmiodrag mechanochemicaltreatmentofserbiankaolinclaytoobtainhighreactivepozzolana |
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