Establishing the Carbonation Profile with Raman Spectroscopy: Effects of Fly Ash and Ground Granulated Blast Furnace Slag
Establishing a carbonation profile is of great significance to the prediction of the service life of reinforced concrete structures. In our previous work, Raman spectroscopy was shown to be an efficient tool for characterizing calcium carbonate (CaCO<sub>3</sub>) polymorphs and their pro...
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doaj-33fbc8f309904317bfd5f7e8923813802021-04-05T23:02:03ZengMDPI AGMaterials1996-19442021-04-01141798179810.3390/ma14071798Establishing the Carbonation Profile with Raman Spectroscopy: Effects of Fly Ash and Ground Granulated Blast Furnace SlagYanfei Yue0Jing Jing Wang1P. A. Muhammed Basheer2Yun Bai3College of Materials Science and Engineering, Chongqing University, 174 Shazheng Street, Shapingba, Chongqing 400044, ChinaCRANN and AMBER Research Centers, Trinity College Dublin, Dublin 2, D02 PN40, IrelandSchool of Civil Engineering, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, UKDepartment of Civil, Environmental and Geomatic Engineering, University College London, Gower Street, London WC1E 6BT, UKEstablishing a carbonation profile is of great significance to the prediction of the service life of reinforced concrete structures. In our previous work, Raman spectroscopy was shown to be an efficient tool for characterizing calcium carbonate (CaCO<sub>3</sub>) polymorphs and their profile in plain Portland cement (PC) matrices. However, as supplementary cementitious materials (SCMs), particularly fly ash (FA) and ground granulated blast furnace slag (GGBS), are widely used in concrete, establishing the carbonation profile without considering the possible effects of these SCMs could be of little significance to the real world. This paper, thus, investigated the effects of FA and GGBS on the working capacity and reliability of Raman spectroscopy for establishing the carbonation profile in PC blends containing SCMs. A thermogravimetry (TG) analysis was also conducted to verify the results from the Raman spectroscopy. The results show that Raman spectroscopy demonstrated a good capacity for differentiating the variation of CaCO<sub>3</sub> contents in FA or GGBS blends. However, the incorporation of FA and GGBS into the PC system caused a few adverse effects on the quantification of CaCO<sub>3</sub> by Raman spectroscopy, which could be attributed to the darker color and weak scatterer nature of FA and the high content of glassy phases in GGBS.https://www.mdpi.com/1996-1944/14/7/1798calcium carbonatecarbonation profilefly ashground granulated blast furnace slagRaman spectroscopy |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Yanfei Yue Jing Jing Wang P. A. Muhammed Basheer Yun Bai |
spellingShingle |
Yanfei Yue Jing Jing Wang P. A. Muhammed Basheer Yun Bai Establishing the Carbonation Profile with Raman Spectroscopy: Effects of Fly Ash and Ground Granulated Blast Furnace Slag Materials calcium carbonate carbonation profile fly ash ground granulated blast furnace slag Raman spectroscopy |
author_facet |
Yanfei Yue Jing Jing Wang P. A. Muhammed Basheer Yun Bai |
author_sort |
Yanfei Yue |
title |
Establishing the Carbonation Profile with Raman Spectroscopy: Effects of Fly Ash and Ground Granulated Blast Furnace Slag |
title_short |
Establishing the Carbonation Profile with Raman Spectroscopy: Effects of Fly Ash and Ground Granulated Blast Furnace Slag |
title_full |
Establishing the Carbonation Profile with Raman Spectroscopy: Effects of Fly Ash and Ground Granulated Blast Furnace Slag |
title_fullStr |
Establishing the Carbonation Profile with Raman Spectroscopy: Effects of Fly Ash and Ground Granulated Blast Furnace Slag |
title_full_unstemmed |
Establishing the Carbonation Profile with Raman Spectroscopy: Effects of Fly Ash and Ground Granulated Blast Furnace Slag |
title_sort |
establishing the carbonation profile with raman spectroscopy: effects of fly ash and ground granulated blast furnace slag |
publisher |
MDPI AG |
series |
Materials |
issn |
1996-1944 |
publishDate |
2021-04-01 |
description |
Establishing a carbonation profile is of great significance to the prediction of the service life of reinforced concrete structures. In our previous work, Raman spectroscopy was shown to be an efficient tool for characterizing calcium carbonate (CaCO<sub>3</sub>) polymorphs and their profile in plain Portland cement (PC) matrices. However, as supplementary cementitious materials (SCMs), particularly fly ash (FA) and ground granulated blast furnace slag (GGBS), are widely used in concrete, establishing the carbonation profile without considering the possible effects of these SCMs could be of little significance to the real world. This paper, thus, investigated the effects of FA and GGBS on the working capacity and reliability of Raman spectroscopy for establishing the carbonation profile in PC blends containing SCMs. A thermogravimetry (TG) analysis was also conducted to verify the results from the Raman spectroscopy. The results show that Raman spectroscopy demonstrated a good capacity for differentiating the variation of CaCO<sub>3</sub> contents in FA or GGBS blends. However, the incorporation of FA and GGBS into the PC system caused a few adverse effects on the quantification of CaCO<sub>3</sub> by Raman spectroscopy, which could be attributed to the darker color and weak scatterer nature of FA and the high content of glassy phases in GGBS. |
topic |
calcium carbonate carbonation profile fly ash ground granulated blast furnace slag Raman spectroscopy |
url |
https://www.mdpi.com/1996-1944/14/7/1798 |
work_keys_str_mv |
AT yanfeiyue establishingthecarbonationprofilewithramanspectroscopyeffectsofflyashandgroundgranulatedblastfurnaceslag AT jingjingwang establishingthecarbonationprofilewithramanspectroscopyeffectsofflyashandgroundgranulatedblastfurnaceslag AT pamuhammedbasheer establishingthecarbonationprofilewithramanspectroscopyeffectsofflyashandgroundgranulatedblastfurnaceslag AT yunbai establishingthecarbonationprofilewithramanspectroscopyeffectsofflyashandgroundgranulatedblastfurnaceslag |
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