Bis(μ-dimesitylborinato-κ2O:O)bis[(2-methylpyridine-κN)lithium]

Bis(μ-dimesitylborinato-κ2O:O)bis[(2-methylpyridine-κN)lithium]

The title compound, [Li2(C18H22BO)2(C6H7N)2], is a lithium dimesitylboroxide dimer in which the lithium cation is also coordinated by one molecule of 2-methylpyridine. At the core of the structure is an Li2O2 four-membered ring. The structure is centrosymmetric with an inversion centre midway betwee...

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Main Authors: James D. Hoefelmeyer, Jung-Ho Son, K. T. Pillai Saravana
Format: Article
Language:English
Published: International Union of Crystallography 2009-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808042748
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spelling doaj-34106473e1d942a09ad8d4c2250cf5b22020-11-24T22:09:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652m179m17910.1107/S1600536808042748Bis(μ-dimesitylborinato-κ2O:O)bis[(2-methylpyridine-κN)lithium]James D. HoefelmeyerJung-Ho SonK. T. Pillai SaravanaThe title compound, [Li2(C18H22BO)2(C6H7N)2], is a lithium dimesitylboroxide dimer in which the lithium cation is also coordinated by one molecule of 2-methylpyridine. At the core of the structure is an Li2O2 four-membered ring. The structure is centrosymmetric with an inversion centre midway between two Li atoms. Intermolecular C—H...π interactions and π–π interactions between the 2-methylpyridine rings exist [centroid–centroid distance = 3.6312 (16) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536808042748
collection DOAJ
language English
format Article
sources DOAJ
author James D. Hoefelmeyer
Jung-Ho Son
K. T. Pillai Saravana
spellingShingle James D. Hoefelmeyer
Jung-Ho Son
K. T. Pillai Saravana
Bis(μ-dimesitylborinato-κ2O:O)bis[(2-methylpyridine-κN)lithium]
Acta Crystallographica Section E
author_facet James D. Hoefelmeyer
Jung-Ho Son
K. T. Pillai Saravana
author_sort James D. Hoefelmeyer
title Bis(μ-dimesitylborinato-κ2O:O)bis[(2-methylpyridine-κN)lithium]
title_short Bis(μ-dimesitylborinato-κ2O:O)bis[(2-methylpyridine-κN)lithium]
title_full Bis(μ-dimesitylborinato-κ2O:O)bis[(2-methylpyridine-κN)lithium]
title_fullStr Bis(μ-dimesitylborinato-κ2O:O)bis[(2-methylpyridine-κN)lithium]
title_full_unstemmed Bis(μ-dimesitylborinato-κ2O:O)bis[(2-methylpyridine-κN)lithium]
title_sort bis(μ-dimesitylborinato-κ2o:o)bis[(2-methylpyridine-κn)lithium]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-02-01
description The title compound, [Li2(C18H22BO)2(C6H7N)2], is a lithium dimesitylboroxide dimer in which the lithium cation is also coordinated by one molecule of 2-methylpyridine. At the core of the structure is an Li2O2 four-membered ring. The structure is centrosymmetric with an inversion centre midway between two Li atoms. Intermolecular C—H...π interactions and π–π interactions between the 2-methylpyridine rings exist [centroid–centroid distance = 3.6312 (16) Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536808042748
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AT junghoson bis956dimesitylborinato9542oobis2methylpyridine954nlithium
AT ktpillaisaravana bis956dimesitylborinato9542oobis2methylpyridine954nlithium
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