Crystal structure of 2-cyano-3,3-bis(ethylsulfanyl)-N-o-tolylacrylamide

Crystal structure of 2-cyano-3,3-bis(ethylsulfanyl)-N-o-tolylacrylamide

In the molecule of the title compound, C15H18N2OS2, the central S2C=C(CN)C moiety is planar (r.m.s. deviation = 0.029 Å). The C=O and C—CN groups are trans to each other across their common C—C bond. In the crystal, one classical and two `weak' hydrogen bonds combine with borderline N...N and S...

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Main Authors: Rasha A. Azzam, Galal H. Elgemeie, Rokia Ramadan, Peter G. Jones
Format: Article
Language:English
Published: International Union of Crystallography 2017-05-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cyanoketene
thioacetal
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017005783
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spelling doaj-34136bc7d7de4c5fb435bd62c7bb53512020-11-24T20:54:59ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-05-0173575275410.1107/S2056989017005783hg5488Crystal structure of 2-cyano-3,3-bis(ethylsulfanyl)-N-o-tolylacrylamideRasha A. Azzam0Galal H. Elgemeie1Rokia Ramadan2Peter G. Jones3Chemistry Department, Faculty of Science, Helwan University, Cairo, EgyptChemistry Department, Faculty of Science, Helwan University, Cairo, EgyptChemistry Department, Faculty of Science, Helwan University, Cairo, EgyptInstitut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Postfach 3329, D-38023 Braunschweig, GermanyIn the molecule of the title compound, C15H18N2OS2, the central S2C=C(CN)C moiety is planar (r.m.s. deviation = 0.029 Å). The C=O and C—CN groups are trans to each other across their common C—C bond. In the crystal, one classical and two `weak' hydrogen bonds combine with borderline N...N and S...S contacts to form layers parallel to (10-2). One ethyl group is disordered over two positions with relative occupancy 0.721/0.279 (7).http://scripts.iucr.org/cgi-bin/paper?S2056989017005783crystal structurecyanoketenethioacetal
collection DOAJ
language English
format Article
sources DOAJ
author Rasha A. Azzam
Galal H. Elgemeie
Rokia Ramadan
Peter G. Jones
spellingShingle Rasha A. Azzam
Galal H. Elgemeie
Rokia Ramadan
Peter G. Jones
Crystal structure of 2-cyano-3,3-bis(ethylsulfanyl)-N-o-tolylacrylamide
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
cyanoketene
thioacetal
author_facet Rasha A. Azzam
Galal H. Elgemeie
Rokia Ramadan
Peter G. Jones
author_sort Rasha A. Azzam
title Crystal structure of 2-cyano-3,3-bis(ethylsulfanyl)-N-o-tolylacrylamide
title_short Crystal structure of 2-cyano-3,3-bis(ethylsulfanyl)-N-o-tolylacrylamide
title_full Crystal structure of 2-cyano-3,3-bis(ethylsulfanyl)-N-o-tolylacrylamide
title_fullStr Crystal structure of 2-cyano-3,3-bis(ethylsulfanyl)-N-o-tolylacrylamide
title_full_unstemmed Crystal structure of 2-cyano-3,3-bis(ethylsulfanyl)-N-o-tolylacrylamide
title_sort crystal structure of 2-cyano-3,3-bis(ethylsulfanyl)-n-o-tolylacrylamide
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2017-05-01
description In the molecule of the title compound, C15H18N2OS2, the central S2C=C(CN)C moiety is planar (r.m.s. deviation = 0.029 Å). The C=O and C—CN groups are trans to each other across their common C—C bond. In the crystal, one classical and two `weak' hydrogen bonds combine with borderline N...N and S...S contacts to form layers parallel to (10-2). One ethyl group is disordered over two positions with relative occupancy 0.721/0.279 (7).
topic crystal structure
cyanoketene
thioacetal
url http://scripts.iucr.org/cgi-bin/paper?S2056989017005783
work_keys_str_mv AT rashaaazzam crystalstructureof2cyano33bisethylsulfanylnotolylacrylamide
AT galalhelgemeie crystalstructureof2cyano33bisethylsulfanylnotolylacrylamide
AT rokiaramadan crystalstructureof2cyano33bisethylsulfanylnotolylacrylamide
AT petergjones crystalstructureof2cyano33bisethylsulfanylnotolylacrylamide
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