Dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable C3 products

The electro-oxidative synthesis of valued chemicals offers to enhance the overall efficiency and economic viability of renewable electrosynthesis systems. Here, the authors use dopant-tuned catalysts to promote the electrosynthesis of dimethyl carbonate from CO and methanol via oxidative carbonylati...

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Main Authors:	Tao-Tao Zhuang, Dae-Hyun Nam, Ziyun Wang, Hui-Hui Li, Christine M. Gabardo, Yi Li, Zhi-Qin Liang, Jun Li, Xiao-Jing Liu, Bin Chen, Wan Ru Leow, Rui Wu, Xue Wang, Fengwang Li, Yanwei Lum, Joshua Wicks, Colin P. O’Brien, Tao Peng, Alexander H. Ip, Tsun-Kong Sham, Shu-Hong Yu, David Sinton, Edward H. Sargent
Format:	Article
Language:	English
Published:	Nature Publishing Group 2019-10-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-019-12788-0

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spelling	doaj-35211011e6c74184a1edf77d819c08e02021-05-11T12:40:25ZengNature Publishing GroupNature Communications2041-17232019-10-011011710.1038/s41467-019-12788-0Dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable C3 productsTao-Tao Zhuang0Dae-Hyun Nam1Ziyun Wang2Hui-Hui Li3Christine M. Gabardo4Yi Li5Zhi-Qin Liang6Jun Li7Xiao-Jing Liu8Bin Chen9Wan Ru Leow10Rui Wu11Xue Wang12Fengwang Li13Yanwei Lum14Joshua Wicks15Colin P. O’Brien16Tao Peng17Alexander H. Ip18Tsun-Kong Sham19Shu-Hong Yu20David Sinton21Edward H. Sargent22Department of Electrical and Computer Engineering, University of TorontoDepartment of Electrical and Computer Engineering, University of TorontoDepartment of Electrical and Computer Engineering, University of TorontoDepartment of Electrical and Computer Engineering, University of TorontoDepartment of Mechanical and Industrial Engineering, University of TorontoDivision of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, CAS Center for Excellence in Nanoscience, Department of Chemistry, University of Science and Technology of ChinaDepartment of Electrical and Computer Engineering, University of TorontoDepartment of Electrical and Computer Engineering, University of TorontoDivision of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, CAS Center for Excellence in Nanoscience, Department of Chemistry, University of Science and Technology of ChinaDepartment of Electrical and Computer Engineering, University of TorontoDepartment of Electrical and Computer Engineering, University of TorontoDivision of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, CAS Center for Excellence in Nanoscience, Department of Chemistry, University of Science and Technology of ChinaDepartment of Electrical and Computer Engineering, University of TorontoDepartment of Electrical and Computer Engineering, University of TorontoDepartment of Electrical and Computer Engineering, University of TorontoDepartment of Electrical and Computer Engineering, University of TorontoDepartment of Mechanical and Industrial Engineering, University of TorontoDepartment of Electrical and Computer Engineering, University of TorontoDepartment of Electrical and Computer Engineering, University of TorontoDepartment of Chemistry, University of Western OntarioDivision of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, CAS Center for Excellence in Nanoscience, Department of Chemistry, University of Science and Technology of ChinaDepartment of Mechanical and Industrial Engineering, University of TorontoDepartment of Electrical and Computer Engineering, University of TorontoThe electro-oxidative synthesis of valued chemicals offers to enhance the overall efficiency and economic viability of renewable electrosynthesis systems. Here, the authors use dopant-tuned catalysts to promote the electrosynthesis of dimethyl carbonate from CO and methanol via oxidative carbonylation.https://doi.org/10.1038/s41467-019-12788-0
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Tao-Tao Zhuang Dae-Hyun Nam Ziyun Wang Hui-Hui Li Christine M. Gabardo Yi Li Zhi-Qin Liang Jun Li Xiao-Jing Liu Bin Chen Wan Ru Leow Rui Wu Xue Wang Fengwang Li Yanwei Lum Joshua Wicks Colin P. O’Brien Tao Peng Alexander H. Ip Tsun-Kong Sham Shu-Hong Yu David Sinton Edward H. Sargent
spellingShingle	Tao-Tao Zhuang Dae-Hyun Nam Ziyun Wang Hui-Hui Li Christine M. Gabardo Yi Li Zhi-Qin Liang Jun Li Xiao-Jing Liu Bin Chen Wan Ru Leow Rui Wu Xue Wang Fengwang Li Yanwei Lum Joshua Wicks Colin P. O’Brien Tao Peng Alexander H. Ip Tsun-Kong Sham Shu-Hong Yu David Sinton Edward H. Sargent Dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable C3 products Nature Communications
author_facet	Tao-Tao Zhuang Dae-Hyun Nam Ziyun Wang Hui-Hui Li Christine M. Gabardo Yi Li Zhi-Qin Liang Jun Li Xiao-Jing Liu Bin Chen Wan Ru Leow Rui Wu Xue Wang Fengwang Li Yanwei Lum Joshua Wicks Colin P. O’Brien Tao Peng Alexander H. Ip Tsun-Kong Sham Shu-Hong Yu David Sinton Edward H. Sargent
author_sort	Tao-Tao Zhuang
title	Dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable C3 products
title_short	Dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable C3 products
title_full	Dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable C3 products
title_fullStr	Dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable C3 products
title_full_unstemmed	Dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable C3 products
title_sort	dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable c3 products
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2019-10-01
description	The electro-oxidative synthesis of valued chemicals offers to enhance the overall efficiency and economic viability of renewable electrosynthesis systems. Here, the authors use dopant-tuned catalysts to promote the electrosynthesis of dimethyl carbonate from CO and methanol via oxidative carbonylation.
url	https://doi.org/10.1038/s41467-019-12788-0
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Dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable C3 products

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