Poly[[bis(dimethylformamide)[μ7-5,5′-(methylenedioxy)diisophthalato]dizinc] dimethylformamide monosolvate]

Poly[[bis(dimethylformamide)[μ7-5,5′-(methylenedioxy)diisophthalato]dizinc] dimethylformamide monosolvate]

In the crystal structure of the title coordination polymer, {[Zn2(C17H8O10)(C3H7NO)2]·C3H7NO}n, the molecular building block (MBB), viz. {Zn2(CO2)4(C3H7NO)2}, comprises two zinc atoms, each bridged by three carboxylate groups. These two Zn atoms exhibit different coordination environmen...

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Main Authors: Hong He, Wen-Ge Qiu, Chuan-Qiang Li
Format: Article
Language:English
Published: International Union of Crystallography 2011-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811037056
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spelling doaj-353e8c1239f649e5b37d7540c97197dc2020-11-25T00:12:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1406m140610.1107/S1600536811037056Poly[[bis(dimethylformamide)[μ7-5,5′-(methylenedioxy)diisophthalato]dizinc] dimethylformamide monosolvate]Hong HeWen-Ge QiuChuan-Qiang LiIn the crystal structure of the title coordination polymer, {[Zn2(C17H8O10)(C3H7NO)2]·C3H7NO}n, the molecular building block (MBB), viz. {Zn2(CO2)4(C3H7NO)2}, comprises two zinc atoms, each bridged by three carboxylate groups. These two Zn atoms exhibit different coordination environments: a distorted coordination intermediate between trigonal–pyramidal, and square–pyramidal formed by the two coordinated dimethylformamide molecules and three carboxylate groups, and a distorted tetrahedral coordination defined by carboxylate groups of which three are bidentate bridging and the fourth is a monodentate ligand. Thus, each ligand connects four MBBs, forming the three-dimensional polymer.http://scripts.iucr.org/cgi-bin/paper?S1600536811037056
collection DOAJ
language English
format Article
sources DOAJ
author Hong He
Wen-Ge Qiu
Chuan-Qiang Li
spellingShingle Hong He
Wen-Ge Qiu
Chuan-Qiang Li
Poly[[bis(dimethylformamide)[μ7-5,5′-(methylenedioxy)diisophthalato]dizinc] dimethylformamide monosolvate]
Acta Crystallographica Section E
author_facet Hong He
Wen-Ge Qiu
Chuan-Qiang Li
author_sort Hong He
title Poly[[bis(dimethylformamide)[μ7-5,5′-(methylenedioxy)diisophthalato]dizinc] dimethylformamide monosolvate]
title_short Poly[[bis(dimethylformamide)[μ7-5,5′-(methylenedioxy)diisophthalato]dizinc] dimethylformamide monosolvate]
title_full Poly[[bis(dimethylformamide)[μ7-5,5′-(methylenedioxy)diisophthalato]dizinc] dimethylformamide monosolvate]
title_fullStr Poly[[bis(dimethylformamide)[μ7-5,5′-(methylenedioxy)diisophthalato]dizinc] dimethylformamide monosolvate]
title_full_unstemmed Poly[[bis(dimethylformamide)[μ7-5,5′-(methylenedioxy)diisophthalato]dizinc] dimethylformamide monosolvate]
title_sort poly[[bis(dimethylformamide)[μ7-5,5′-(methylenedioxy)diisophthalato]dizinc] dimethylformamide monosolvate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-10-01
description In the crystal structure of the title coordination polymer, {[Zn2(C17H8O10)(C3H7NO)2]·C3H7NO}n, the molecular building block (MBB), viz. {Zn2(CO2)4(C3H7NO)2}, comprises two zinc atoms, each bridged by three carboxylate groups. These two Zn atoms exhibit different coordination environments: a distorted coordination intermediate between trigonal–pyramidal, and square–pyramidal formed by the two coordinated dimethylformamide molecules and three carboxylate groups, and a distorted tetrahedral coordination defined by carboxylate groups of which three are bidentate bridging and the fourth is a monodentate ligand. Thus, each ligand connects four MBBs, forming the three-dimensional polymer.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811037056
work_keys_str_mv AT honghe polybisdimethylformamideamp956755amp8242methylenedioxydiisophthalatodizincdimethylformamidemonosolvate
AT wengeqiu polybisdimethylformamideamp956755amp8242methylenedioxydiisophthalatodizincdimethylformamidemonosolvate
AT chuanqiangli polybisdimethylformamideamp956755amp8242methylenedioxydiisophthalatodizincdimethylformamidemonosolvate
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